Allosteric Recognition of Homomeric and Heteromeric Pairs of Monosaccharides by a Foldamer Capsule

The recognition of either homomeric or heteromeric pairs of pentoses in an aromatic oligoamide double helical foldamer capsule was evidenced by circular dichroism (CD), NMR spectroscopy, and X‐ray crystallography. The cavity of the host was predicted to be large enough to accommodate simultaneously...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-03, Vol.59 (14), p.5797-5805
Hauptverfasser:	Mateus, Pedro, Chandramouli, Nagula, Mackereth, Cameron D., Kauffmann, Brice, Ferrand, Yann, Huc, Ivan
Format:	Artikel
Sprache:	eng
Schlagworte:	Allosteric properties allostery Carbohydrates Chemical Sciences Circular dichroism Crystallography Dichroism Double-stranded foldamers helical capsules Magnetic resonance spectroscopy molecular recognition Monosaccharides NMR NMR spectroscopy Nuclear magnetic resonance Organic chemistry Recognition Saccharides Sequestering
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