Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts

The non-metal cation pentaborate(1−) salt [ p -H 2 NC 6 H 4 CH 2 NH 3 ][B 5 O 6 (OH) 4 ]·1/2H 2 O ( 1 ) was synthesised from B(OH) 3 and p -H 2 NC 6 H 4 CH 2 NH 2 and crystallized from aqueous solution. Compound 1 was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-r...

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