Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts
The non-metal cation pentaborate(1−) salt [ p -H 2 NC 6 H 4 CH 2 NH 3 ][B 5 O 6 (OH) 4 ]·1/2H 2 O ( 1 ) was synthesised from B(OH) 3 and p -H 2 NC 6 H 4 CH 2 NH 2 and crystallized from aqueous solution. Compound 1 was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-r...
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| Veröffentlicht in: | Journal of cluster science 2017-07, Vol.28 (4), p.2087-2095 |
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| creator | Beckett, Michael A. Coles, Simon J. Horton, Peter N. Jones, Charlotte L. Krueger, Kerstin |
| description | The non-metal cation pentaborate(1−) salt [
p
-H
2
NC
6
H
4
CH
2
NH
3
][B
5
O
6
(OH)
4
]·1/2H
2
O (
1
) was synthesised from B(OH)
3
and
p
-H
2
NC
6
H
4
CH
2
NH
2
and crystallized from aqueous solution. Compound
1
was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-ray diffraction methods and it was found to crystallize in the non-centrosymmetric point group
P
2
1
. Powder SHG measurements on
1
and some related alkylammonium pentaborate salts, [NH
3
CMe
2
(CH
2
OH)][B
5
O
6
(OH)
4
], [NH
3
CMe(CH
2
OH)
2
][B
5
O
6
(OH)
4
] and [NH
3
CHMeCH
2
OH][B
5
O
6
(OH)
4
], a substituted imidazolium salt, [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], a substituted piperidinium salt, [(CH
2
)
5
NH(CH
2
CH
2
OH)][B
5
O
6
(OH)
4
], and a substituted pyrrolidinium salt, [
S
-(+)-2-(HOCH
2
)C
4
H
7
NH
2
][B
5
O
6
(OH)
4
], were determined. Compound
1
and all compounds, except [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], showed some weak SHG activity with SHG efficiencies of 0.1–0.2 relative to that of KH
2
PO
4
(KDP). |
| doi_str_mv | 10.1007/s10876-017-1205-1 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7098061</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918291784</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3291-94c7883ab9e750abbf93b09a774314fe38008698d593ad9b1faa38ca1d89d2253</originalsourceid><addsrcrecordid>eNp1UctKJDEUDaL4_gB3ATcKRm-SqkqyEWZ6RmugscRWEERCqiqlJd2VnqR6wD9wMav5Gfd-il8yaVoUFy7Czb0559xDDkI7FA4pgDgKFKTICFBBKIOU0CW0TlPBiJQZW453SIAIJuQa2gjhAQCU5HwVrXHGWMYysY7-jh67_t6GNhzg64sfeNTP6tYGbLoanw0LfO7d1Pp-PnINvpmSnJ0NsjwZxJrz25vvaZHtFfl-cvvyTI9YzoovqCM3sfjCjk1va3xuu96Uzsdmj74-_dvHIzPuwxZaacw42O23uomuTn5eDnIyLE5_Db4NScWZokQllZCSm1JZkYIpy0bxEpQRIuE0aSyXADJTsk4VN7UqaWMMl5WhtVQ1YynfRMcL3emsnNi6im68GeupbyfGP2pnWv35pWvv9Z37o0X8QMhoFNh9E_Du98yGXj-4me-iZx0NyniETCKKLlCVdyF427xvoKDnAepFgDoGqOcB6rkyW3BCxHZ31n8of036D00omqM</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918291784</pqid></control><display><type>article</type><title>Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts</title><source>SpringerLink Journals</source><source>ProQuest Central</source><creator>Beckett, Michael A. ; Coles, Simon J. ; Horton, Peter N. ; Jones, Charlotte L. ; Krueger, Kerstin</creator><creatorcontrib>Beckett, Michael A. ; Coles, Simon J. ; Horton, Peter N. ; Jones, Charlotte L. ; Krueger, Kerstin</creatorcontrib><description>The non-metal cation pentaborate(1−) salt [
p
-H
2
NC
6
H
4
CH
2
NH
3
][B
5
O
6
(OH)
4
]·1/2H
2
O (
1
) was synthesised from B(OH)
3
and
p
-H
2
NC
6
H
4
CH
2
NH
2
and crystallized from aqueous solution. Compound
1
was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-ray diffraction methods and it was found to crystallize in the non-centrosymmetric point group
P
2
1
. Powder SHG measurements on
1
and some related alkylammonium pentaborate salts, [NH
3
CMe
2
(CH
2
OH)][B
5
O
6
(OH)
4
], [NH
3
CMe(CH
2
OH)
2
][B
5
O
6
(OH)
4
] and [NH
3
CHMeCH
2
OH][B
5
O
6
(OH)
4
], a substituted imidazolium salt, [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], a substituted piperidinium salt, [(CH
2
)
5
NH(CH
2
CH
2
OH)][B
5
O
6
(OH)
4
], and a substituted pyrrolidinium salt, [
S
-(+)-2-(HOCH
2
)C
4
H
7
NH
2
][B
5
O
6
(OH)
4
], were determined. Compound
1
and all compounds, except [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], showed some weak SHG activity with SHG efficiencies of 0.1–0.2 relative to that of KH
2
PO
4
(KDP).</description><identifier>ISSN: 1040-7278</identifier><identifier>EISSN: 1572-8862</identifier><identifier>DOI: 10.1007/s10876-017-1205-1</identifier><identifier>PMID: 32226267</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aqueous solutions ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Crystallization ; Crystals ; Decomposition ; Inorganic Chemistry ; Investigations ; Nanochemistry ; NMR ; Nuclear magnetic resonance ; Original Paper ; Physical Chemistry ; Potassium phosphates ; Single crystals ; Substitutes</subject><ispartof>Journal of cluster science, 2017-07, Vol.28 (4), p.2087-2095</ispartof><rights>The Author(s) 2017</rights><rights>The Author(s) 2017. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3291-94c7883ab9e750abbf93b09a774314fe38008698d593ad9b1faa38ca1d89d2253</citedby><cites>FETCH-LOGICAL-c3291-94c7883ab9e750abbf93b09a774314fe38008698d593ad9b1faa38ca1d89d2253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10876-017-1205-1$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918291784?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>230,314,776,780,881,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Beckett, Michael A.</creatorcontrib><creatorcontrib>Coles, Simon J.</creatorcontrib><creatorcontrib>Horton, Peter N.</creatorcontrib><creatorcontrib>Jones, Charlotte L.</creatorcontrib><creatorcontrib>Krueger, Kerstin</creatorcontrib><title>Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts</title><title>Journal of cluster science</title><addtitle>J Clust Sci</addtitle><description>The non-metal cation pentaborate(1−) salt [
p
-H
2
NC
6
H
4
CH
2
NH
3
][B
5
O
6
(OH)
4
]·1/2H
2
O (
1
) was synthesised from B(OH)
3
and
p
-H
2
NC
6
H
4
CH
2
NH
2
and crystallized from aqueous solution. Compound
1
was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-ray diffraction methods and it was found to crystallize in the non-centrosymmetric point group
P
2
1
. Powder SHG measurements on
1
and some related alkylammonium pentaborate salts, [NH
3
CMe
2
(CH
2
OH)][B
5
O
6
(OH)
4
], [NH
3
CMe(CH
2
OH)
2
][B
5
O
6
(OH)
4
] and [NH
3
CHMeCH
2
OH][B
5
O
6
(OH)
4
], a substituted imidazolium salt, [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], a substituted piperidinium salt, [(CH
2
)
5
NH(CH
2
CH
2
OH)][B
5
O
6
(OH)
4
], and a substituted pyrrolidinium salt, [
S
-(+)-2-(HOCH
2
)C
4
H
7
NH
2
][B
5
O
6
(OH)
4
], were determined. Compound
1
and all compounds, except [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], showed some weak SHG activity with SHG efficiencies of 0.1–0.2 relative to that of KH
2
PO
4
(KDP).</description><subject>Aqueous solutions</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallization</subject><subject>Crystals</subject><subject>Decomposition</subject><subject>Inorganic Chemistry</subject><subject>Investigations</subject><subject>Nanochemistry</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Potassium phosphates</subject><subject>Single crystals</subject><subject>Substitutes</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp1UctKJDEUDaL4_gB3ATcKRm-SqkqyEWZ6RmugscRWEERCqiqlJd2VnqR6wD9wMav5Gfd-il8yaVoUFy7Czb0559xDDkI7FA4pgDgKFKTICFBBKIOU0CW0TlPBiJQZW453SIAIJuQa2gjhAQCU5HwVrXHGWMYysY7-jh67_t6GNhzg64sfeNTP6tYGbLoanw0LfO7d1Pp-PnINvpmSnJ0NsjwZxJrz25vvaZHtFfl-cvvyTI9YzoovqCM3sfjCjk1va3xuu96Uzsdmj74-_dvHIzPuwxZaacw42O23uomuTn5eDnIyLE5_Db4NScWZokQllZCSm1JZkYIpy0bxEpQRIuE0aSyXADJTsk4VN7UqaWMMl5WhtVQ1YynfRMcL3emsnNi6im68GeupbyfGP2pnWv35pWvv9Z37o0X8QMhoFNh9E_Du98yGXj-4me-iZx0NyniETCKKLlCVdyF427xvoKDnAepFgDoGqOcB6rkyW3BCxHZ31n8of036D00omqM</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>Beckett, Michael A.</creator><creator>Coles, Simon J.</creator><creator>Horton, Peter N.</creator><creator>Jones, Charlotte L.</creator><creator>Krueger, Kerstin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>5PM</scope></search><sort><creationdate>20170701</creationdate><title>Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts</title><author>Beckett, Michael A. ; Coles, Simon J. ; Horton, Peter N. ; Jones, Charlotte L. ; Krueger, Kerstin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3291-94c7883ab9e750abbf93b09a774314fe38008698d593ad9b1faa38ca1d89d2253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aqueous solutions</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallization</topic><topic>Crystals</topic><topic>Decomposition</topic><topic>Inorganic Chemistry</topic><topic>Investigations</topic><topic>Nanochemistry</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Potassium phosphates</topic><topic>Single crystals</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Beckett, Michael A.</creatorcontrib><creatorcontrib>Coles, Simon J.</creatorcontrib><creatorcontrib>Horton, Peter N.</creatorcontrib><creatorcontrib>Jones, Charlotte L.</creatorcontrib><creatorcontrib>Krueger, Kerstin</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Beckett, Michael A.</au><au>Coles, Simon J.</au><au>Horton, Peter N.</au><au>Jones, Charlotte L.</au><au>Krueger, Kerstin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts</atitle><jtitle>Journal of cluster science</jtitle><stitle>J Clust Sci</stitle><date>2017-07-01</date><risdate>2017</risdate><volume>28</volume><issue>4</issue><spage>2087</spage><epage>2095</epage><pages>2087-2095</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>The non-metal cation pentaborate(1−) salt [
p
-H
2
NC
6
H
4
CH
2
NH
3
][B
5
O
6
(OH)
4
]·1/2H
2
O (
1
) was synthesised from B(OH)
3
and
p
-H
2
NC
6
H
4
CH
2
NH
2
and crystallized from aqueous solution. Compound
1
was characterized by thermal (TGA/DSC), spectroscopic (IR, NMR) and single-crystal X-ray diffraction methods and it was found to crystallize in the non-centrosymmetric point group
P
2
1
. Powder SHG measurements on
1
and some related alkylammonium pentaborate salts, [NH
3
CMe
2
(CH
2
OH)][B
5
O
6
(OH)
4
], [NH
3
CMe(CH
2
OH)
2
][B
5
O
6
(OH)
4
] and [NH
3
CHMeCH
2
OH][B
5
O
6
(OH)
4
], a substituted imidazolium salt, [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], a substituted piperidinium salt, [(CH
2
)
5
NH(CH
2
CH
2
OH)][B
5
O
6
(OH)
4
], and a substituted pyrrolidinium salt, [
S
-(+)-2-(HOCH
2
)C
4
H
7
NH
2
][B
5
O
6
(OH)
4
], were determined. Compound
1
and all compounds, except [1,2,3-Me
3
C
3
H
2
N
2
][B
5
O
6
(OH)
4
], showed some weak SHG activity with SHG efficiencies of 0.1–0.2 relative to that of KH
2
PO
4
(KDP).</abstract><cop>New York</cop><pub>Springer US</pub><pmid>32226267</pmid><doi>10.1007/s10876-017-1205-1</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1040-7278 |
| ispartof | Journal of cluster science, 2017-07, Vol.28 (4), p.2087-2095 |
| issn | 1040-7278 1572-8862 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7098061 |
| source | SpringerLink Journals; ProQuest Central |
| subjects | Aqueous solutions Catalysis Chemistry Chemistry and Materials Science Crystallization Crystals Decomposition Inorganic Chemistry Investigations Nanochemistry NMR Nuclear magnetic resonance Original Paper Physical Chemistry Potassium phosphates Single crystals Substitutes |
| title | Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts |
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