Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy
Aqueous glycerol was identified as a renewable reaction medium for metalla‐electrocatalyzed C−H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt‐catalyzed C−H/N−H functionalizations under mild conditions. The cobalta‐electrocatalysis manifold occurred w...
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| Veröffentlicht in: | ChemSusChem 2020-02, Vol.13 (4), p.668-671 |
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| creator | Meyer, Tjark H. Chesnokov, Gleb A. Ackermann, Lutz |
| description | Aqueous glycerol was identified as a renewable reaction medium for metalla‐electrocatalyzed C−H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt‐catalyzed C−H/N−H functionalizations under mild conditions. The cobalta‐electrocatalysis manifold occurred with high levels of chemo‐ and positional selectivity and allowed for electrochemical C−H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by the direct use of renewable solar and wind energy.
Renewing C−H activation: Renewable resources prove amenable to enable cobalta‐electrocatalyzed C−H activations in aqueous glycerol, empowered by solar or wind energy. The cobalta‐electrocatalysis manifold occurs with high levels of chemo‐ and positional selectivity and allows for electrochemical C−H activations with broad substrate scope. |
| doi_str_mv | 10.1002/cssc.202000057 |
| format | Article |
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Renewing C−H activation: Renewable resources prove amenable to enable cobalta‐electrocatalyzed C−H activations in aqueous glycerol, empowered by solar or wind energy. The cobalta‐electrocatalysis manifold occurs with high levels of chemo‐ and positional selectivity and allows for electrochemical C−H activations with broad substrate scope.</description><identifier>ISSN: 1864-5631</identifier><identifier>ISSN: 1864-564X</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.202000057</identifier><identifier>PMID: 31917522</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Alternative energy ; biomass ; cobalt ; Communication ; Communications ; C−H activation ; electrochemistry ; Glycerol ; renewable energy ; Selectivity ; Solar energy ; Substrates ; sustainability ; Wind power</subject><ispartof>ChemSusChem, 2020-02, Vol.13 (4), p.668-671</ispartof><rights>2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.</rights><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4687-d8b1d620b93dfb9aa07c02dcf625cf2e804b564103504e1520817eaebae29753</citedby><cites>FETCH-LOGICAL-c4687-d8b1d620b93dfb9aa07c02dcf625cf2e804b564103504e1520817eaebae29753</cites><orcidid>0000-0001-7034-8772 ; 0000-0002-7909-0250</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.202000057$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.202000057$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31917522$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Meyer, Tjark H.</creatorcontrib><creatorcontrib>Chesnokov, Gleb A.</creatorcontrib><creatorcontrib>Ackermann, Lutz</creatorcontrib><title>Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>Aqueous glycerol was identified as a renewable reaction medium for metalla‐electrocatalyzed C−H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt‐catalyzed C−H/N−H functionalizations under mild conditions. The cobalta‐electrocatalysis manifold occurred with high levels of chemo‐ and positional selectivity and allowed for electrochemical C−H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by the direct use of renewable solar and wind energy.
Renewing C−H activation: Renewable resources prove amenable to enable cobalta‐electrocatalyzed C−H activations in aqueous glycerol, empowered by solar or wind energy. The cobalta‐electrocatalysis manifold occurs with high levels of chemo‐ and positional selectivity and allows for electrochemical C−H activations with broad substrate scope.</description><subject>Alternative energy</subject><subject>biomass</subject><subject>cobalt</subject><subject>Communication</subject><subject>Communications</subject><subject>C−H activation</subject><subject>electrochemistry</subject><subject>Glycerol</subject><subject>renewable energy</subject><subject>Selectivity</subject><subject>Solar energy</subject><subject>Substrates</subject><subject>sustainability</subject><subject>Wind power</subject><issn>1864-5631</issn><issn>1864-564X</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkU9rFDEchoMotlavHiXgxcuuSWaSzHgQ6ri2QkFxC3oLSeY3NSU7aZOZXcaTR4_iR-wnMcvW9c_FQEhInjzk5UXoMSVzSgh7blOyc0YYyYPLO-iQVqKccVF-urvfF_QAPUjpkhBBaiHuo4OC1lRyxg7R2ASj_aBvvn5feLBDDFYP2k9foMXNzbcfp_jYDm6tBxd67Hr8yoWVTinjryG6daZO_GQhBv8Cvw8biPnETPgD9LDRxgP-6PoW6zyXweuIFz3Ei-khutdpn-DR7XqEzt8szpvT2dm7k7fN8dnMlqKSs7YytBWMmLpoO1NrTaQlrLWdYNx2DCpSmhyVkoKTEihnpKISNBgNrJa8OEIvd9qr0aygtdAPUXt1Fd1Kx0kF7dTfN737rC7CWkkiOONbwbNbQQzXI6RBrVyy4L3uIYxJsaLgVApZbdGn_6CXYYx9TpcpweqSVbzO1HxH2RhSitDtP0OJ2haqtoWqfaH5wZM_I-zxXw1moN4BG-dh-o9ONctl81v-EyKasTE</recordid><startdate>20200221</startdate><enddate>20200221</enddate><creator>Meyer, Tjark H.</creator><creator>Chesnokov, Gleb A.</creator><creator>Ackermann, Lutz</creator><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7034-8772</orcidid><orcidid>https://orcid.org/0000-0002-7909-0250</orcidid></search><sort><creationdate>20200221</creationdate><title>Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy</title><author>Meyer, Tjark H. ; Chesnokov, Gleb A. ; Ackermann, Lutz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4687-d8b1d620b93dfb9aa07c02dcf625cf2e804b564103504e1520817eaebae29753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alternative energy</topic><topic>biomass</topic><topic>cobalt</topic><topic>Communication</topic><topic>Communications</topic><topic>C−H activation</topic><topic>electrochemistry</topic><topic>Glycerol</topic><topic>renewable energy</topic><topic>Selectivity</topic><topic>Solar energy</topic><topic>Substrates</topic><topic>sustainability</topic><topic>Wind power</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meyer, Tjark H.</creatorcontrib><creatorcontrib>Chesnokov, Gleb A.</creatorcontrib><creatorcontrib>Ackermann, Lutz</creatorcontrib><collection>Wiley-Blackwell Open Access Titles</collection><collection>Wiley Free Content</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meyer, Tjark H.</au><au>Chesnokov, Gleb A.</au><au>Ackermann, Lutz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2020-02-21</date><risdate>2020</risdate><volume>13</volume><issue>4</issue><spage>668</spage><epage>671</epage><pages>668-671</pages><issn>1864-5631</issn><issn>1864-564X</issn><eissn>1864-564X</eissn><abstract>Aqueous glycerol was identified as a renewable reaction medium for metalla‐electrocatalyzed C−H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt‐catalyzed C−H/N−H functionalizations under mild conditions. The cobalta‐electrocatalysis manifold occurred with high levels of chemo‐ and positional selectivity and allowed for electrochemical C−H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by the direct use of renewable solar and wind energy.
Renewing C−H activation: Renewable resources prove amenable to enable cobalta‐electrocatalyzed C−H activations in aqueous glycerol, empowered by solar or wind energy. The cobalta‐electrocatalysis manifold occurs with high levels of chemo‐ and positional selectivity and allows for electrochemical C−H activations with broad substrate scope.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>31917522</pmid><doi>10.1002/cssc.202000057</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-7034-8772</orcidid><orcidid>https://orcid.org/0000-0002-7909-0250</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Alternative energy biomass cobalt Communication Communications C−H activation electrochemistry Glycerol renewable energy Selectivity Solar energy Substrates sustainability Wind power |
| title | Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy |
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