Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials
We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of −3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (E red ≈ −1.9 to −2.9 V). The resultant ary...
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| Veröffentlicht in: | Journal of the American Chemical Society 2020-02, Vol.142 (5), p.2087-2092 |
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| container_end_page | 2092 |
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| container_issue | 5 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 142 |
| creator | Kim, Hyunwoo Kim, Hyungjun Lambert, Tristan H Lin, Song |
| description | We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of −3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (E red ≈ −1.9 to −2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products. |
| doi_str_mv | 10.1021/jacs.9b10678 |
| format | Article |
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The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.</description><subject>aromatic compounds</subject><subject>electricity</subject><subject>free radicals</subject><subject>photocatalysis</subject><issn>0002-7863</issn><issn>1520-5126</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkctP4zAQxi3ECkrhxhnlyIGwfsSOwwGpQjxW6mpXqJwtx520rtK42A6i_z2JCGVXQuI0Gs033zx-CJ0SfEkwJT9X2oTLoiRY5HIPjQinOOWEin00whjTNJeCHaKjEFZdmlFJDtAhIwUnrMAjVD3CvDXRvkByW4OJ3m2WLjqjo663wYar5Df4hW0WQ9kaG7eJbubJ1C6WMZm5ZGKWFvr-1-hhDcng6Jrkr4vQRKvrcIx-VF2AkyGO0dPd7ezmIZ3-uf91M5mmmnMWU53TMpcZiCIvuCmxKAlwrWmJOcuMySSjOcOyFBhkVYA2MK9oSSjhRguSZ2yMrt99N225hrnpxntdq423a-23ymmr_q80dqkW7kXlmDLZ_WSMzgcD755bCFGtbTBQ17oB1wZFC8llwTPBvpeyjAjaoehdL96lxrsQPFS7jQhWPUXVU1QDxU5-9u8VO_EHts_RfdfKtb7pnvq11xtCrqfU</recordid><startdate>20200205</startdate><enddate>20200205</enddate><creator>Kim, Hyunwoo</creator><creator>Kim, Hyungjun</creator><creator>Lambert, Tristan H</creator><creator>Lin, Song</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-8880-6476</orcidid><orcidid>https://orcid.org/0000-0002-7204-3718</orcidid><orcidid>https://orcid.org/0000-0002-7720-3290</orcidid></search><sort><creationdate>20200205</creationdate><title>Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials</title><author>Kim, Hyunwoo ; Kim, Hyungjun ; Lambert, Tristan H ; Lin, Song</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a553t-a72b784e69795cb06b1e5aa2b0534cc48327308b60e8f9eacedf2b1215ca61743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>aromatic compounds</topic><topic>electricity</topic><topic>free radicals</topic><topic>photocatalysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Hyunwoo</creatorcontrib><creatorcontrib>Kim, Hyungjun</creatorcontrib><creatorcontrib>Lambert, Tristan H</creatorcontrib><creatorcontrib>Lin, Song</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Hyunwoo</au><au>Kim, Hyungjun</au><au>Lambert, Tristan H</au><au>Lin, Song</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. 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| source | ACS Publications |
| subjects | aromatic compounds electricity free radicals photocatalysis |
| title | Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials |
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