Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties
The copolymerization of styrene (St) with a bioderived monomer, pentadecylphenyl methacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work. The copolymerization reactivity ratio was calculated using the composition data obtained from H NMR spectroscopy, applying...
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| Veröffentlicht in: | Polymers 2020-01, Vol.12 (1), p.97 |
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| creator | Muringayil Joseph, Tomy Murali Nair, Sumi Kattimuttathu Ittara, Suresh Haponiuk, Józef T Thomas, Sabu |
| description | The copolymerization of styrene (St) with a bioderived monomer, pentadecylphenyl methacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work. The copolymerization reactivity ratio was calculated using the composition data obtained from
H NMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r
= 0.93) and PDPMA (r
= 0.05) suggested random copolymerization of the two monomers with alternation. The copolymerization conversion increased with increasing PDPMA concentration of the feed, upto 70 wt % PDPMA, but decreased thereafter. The molecular weight determined by gel permeation chromatography was lower than the theoretical values and the polydispersity increased from 1.32 to 2.19, with increasing PDPMA content in the feed. The influence of styrene content on the glass transition and thermal decomposition behavior of the copolymers was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis, respectively. Morphological characterization by transmission electron microscopy (TEM) revealed a phase separated soft core-hard shell type structure. The complex viscosity and adhesion properties like peel strength and lap shear strength of the copolymer on different substrates increased with increasing styrene content. |
| doi_str_mv | 10.3390/polym12010097 |
| format | Article |
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H NMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r
= 0.93) and PDPMA (r
= 0.05) suggested random copolymerization of the two monomers with alternation. The copolymerization conversion increased with increasing PDPMA concentration of the feed, upto 70 wt % PDPMA, but decreased thereafter. The molecular weight determined by gel permeation chromatography was lower than the theoretical values and the polydispersity increased from 1.32 to 2.19, with increasing PDPMA content in the feed. The influence of styrene content on the glass transition and thermal decomposition behavior of the copolymers was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis, respectively. Morphological characterization by transmission electron microscopy (TEM) revealed a phase separated soft core-hard shell type structure. The complex viscosity and adhesion properties like peel strength and lap shear strength of the copolymer on different substrates increased with increasing styrene content.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym12010097</identifier><identifier>PMID: 31947916</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Acids ; Chloride ; Copolymerization ; Copolymers ; Crystallization ; Differential scanning calorimetry ; Experiments ; Glass transition ; Graphene ; Hydrogenation ; Liquid chromatography ; Monomers ; Morphology ; Nanocomposites ; NMR spectroscopy ; Peel strength ; Polydispersity ; Polymerization ; Polymers ; Shear strength ; Styrenes ; Substrates ; Surfactants ; Sustainability ; Sustainable materials ; Textiles ; Thermal decomposition ; Thermogravimetric analysis ; Thermomechanical properties</subject><ispartof>Polymers, 2020-01, Vol.12 (1), p.97</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 by the authors. 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-9f9a126fc9069ee4ccdfad021819126983c7685a6c220baa762c88bf78ae84b53</citedby><cites>FETCH-LOGICAL-c415t-9f9a126fc9069ee4ccdfad021819126983c7685a6c220baa762c88bf78ae84b53</cites><orcidid>0000-0002-9206-3900 ; 0000-0002-7630-5834 ; 0000-0001-6377-7050 ; 0000-0002-9220-8823</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7023656/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7023656/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31947916$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Muringayil Joseph, Tomy</creatorcontrib><creatorcontrib>Murali Nair, Sumi</creatorcontrib><creatorcontrib>Kattimuttathu Ittara, Suresh</creatorcontrib><creatorcontrib>Haponiuk, Józef T</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><title>Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>The copolymerization of styrene (St) with a bioderived monomer, pentadecylphenyl methacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work. The copolymerization reactivity ratio was calculated using the composition data obtained from
H NMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r
= 0.93) and PDPMA (r
= 0.05) suggested random copolymerization of the two monomers with alternation. The copolymerization conversion increased with increasing PDPMA concentration of the feed, upto 70 wt % PDPMA, but decreased thereafter. The molecular weight determined by gel permeation chromatography was lower than the theoretical values and the polydispersity increased from 1.32 to 2.19, with increasing PDPMA content in the feed. The influence of styrene content on the glass transition and thermal decomposition behavior of the copolymers was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis, respectively. Morphological characterization by transmission electron microscopy (TEM) revealed a phase separated soft core-hard shell type structure. The complex viscosity and adhesion properties like peel strength and lap shear strength of the copolymer on different substrates increased with increasing styrene content.</description><subject>Acids</subject><subject>Chloride</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Crystallization</subject><subject>Differential scanning calorimetry</subject><subject>Experiments</subject><subject>Glass transition</subject><subject>Graphene</subject><subject>Hydrogenation</subject><subject>Liquid chromatography</subject><subject>Monomers</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>NMR spectroscopy</subject><subject>Peel strength</subject><subject>Polydispersity</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Shear strength</subject><subject>Styrenes</subject><subject>Substrates</subject><subject>Surfactants</subject><subject>Sustainability</subject><subject>Sustainable materials</subject><subject>Textiles</subject><subject>Thermal decomposition</subject><subject>Thermogravimetric analysis</subject><subject>Thermomechanical properties</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkV1rFDEUhoMottReeisD3lToaD5mMhMvhGX9hIoLrdfhbOaMkzKTjElWGP-Cf9psW5fW3CQkD8_Jy0vIc0ZfC6Hom9mPy8Q4ZZSq5hE55rQRZSUkfXzvfEROY7ymeVW1lKx5So4EU1WjmDwmf9b-RoLB_oZkvSt8X1ymJaDDAlxXbNAl6NAs4zygW8YJ0wAmLCMkLM427zdfV6_eFpeLSwNGG8-L9QABTDoIz4urAcPkJzQDOGtgvPGuuj2f522CnzEki_EZedLDGPH0bj8h3z9-uFp_Li--ffqyXl2UpmJ1KlWvgHHZG0WlQqyM6XroKGctU_letcI0sq1BGs7pFqCR3LTttm9awLba1uKEvLv1zrvthJ3JCQOMeg52grBoD1Y_fHF20D_8L91QLmQts-DsThD8zx3GpCcbDY4jOPS7qLmomGRVzVlGX_6HXvtdcDme5nVNeb0nM1XeUib4GAP2h88wqvdN6wdNZ_7F_QQH-l-v4i95I6gl</recordid><startdate>20200104</startdate><enddate>20200104</enddate><creator>Muringayil Joseph, Tomy</creator><creator>Murali Nair, Sumi</creator><creator>Kattimuttathu Ittara, Suresh</creator><creator>Haponiuk, Józef T</creator><creator>Thomas, Sabu</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-9206-3900</orcidid><orcidid>https://orcid.org/0000-0002-7630-5834</orcidid><orcidid>https://orcid.org/0000-0001-6377-7050</orcidid><orcidid>https://orcid.org/0000-0002-9220-8823</orcidid></search><sort><creationdate>20200104</creationdate><title>Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties</title><author>Muringayil Joseph, Tomy ; Murali Nair, Sumi ; Kattimuttathu Ittara, Suresh ; Haponiuk, Józef T ; Thomas, Sabu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-9f9a126fc9069ee4ccdfad021819126983c7685a6c220baa762c88bf78ae84b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acids</topic><topic>Chloride</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Crystallization</topic><topic>Differential scanning calorimetry</topic><topic>Experiments</topic><topic>Glass transition</topic><topic>Graphene</topic><topic>Hydrogenation</topic><topic>Liquid chromatography</topic><topic>Monomers</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>NMR spectroscopy</topic><topic>Peel strength</topic><topic>Polydispersity</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Shear strength</topic><topic>Styrenes</topic><topic>Substrates</topic><topic>Surfactants</topic><topic>Sustainability</topic><topic>Sustainable materials</topic><topic>Textiles</topic><topic>Thermal decomposition</topic><topic>Thermogravimetric analysis</topic><topic>Thermomechanical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Muringayil Joseph, Tomy</creatorcontrib><creatorcontrib>Murali Nair, Sumi</creatorcontrib><creatorcontrib>Kattimuttathu Ittara, Suresh</creatorcontrib><creatorcontrib>Haponiuk, Józef T</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Muringayil Joseph, Tomy</au><au>Murali Nair, Sumi</au><au>Kattimuttathu Ittara, Suresh</au><au>Haponiuk, Józef T</au><au>Thomas, Sabu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2020-01-04</date><risdate>2020</risdate><volume>12</volume><issue>1</issue><spage>97</spage><pages>97-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>The copolymerization of styrene (St) with a bioderived monomer, pentadecylphenyl methacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work. The copolymerization reactivity ratio was calculated using the composition data obtained from
H NMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r
= 0.93) and PDPMA (r
= 0.05) suggested random copolymerization of the two monomers with alternation. The copolymerization conversion increased with increasing PDPMA concentration of the feed, upto 70 wt % PDPMA, but decreased thereafter. The molecular weight determined by gel permeation chromatography was lower than the theoretical values and the polydispersity increased from 1.32 to 2.19, with increasing PDPMA content in the feed. The influence of styrene content on the glass transition and thermal decomposition behavior of the copolymers was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis, respectively. Morphological characterization by transmission electron microscopy (TEM) revealed a phase separated soft core-hard shell type structure. The complex viscosity and adhesion properties like peel strength and lap shear strength of the copolymer on different substrates increased with increasing styrene content.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>31947916</pmid><doi>10.3390/polym12010097</doi><orcidid>https://orcid.org/0000-0002-9206-3900</orcidid><orcidid>https://orcid.org/0000-0002-7630-5834</orcidid><orcidid>https://orcid.org/0000-0001-6377-7050</orcidid><orcidid>https://orcid.org/0000-0002-9220-8823</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Acids Chloride Copolymerization Copolymers Crystallization Differential scanning calorimetry Experiments Glass transition Graphene Hydrogenation Liquid chromatography Monomers Morphology Nanocomposites NMR spectroscopy Peel strength Polydispersity Polymerization Polymers Shear strength Styrenes Substrates Surfactants Sustainability Sustainable materials Textiles Thermal decomposition Thermogravimetric analysis Thermomechanical properties |
| title | Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties |
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