Comparison of The Sorption Kinetics of Lead(II) and Zinc(II) on Titanium Phosphate Ion-Exchanger
The treatment of heavy metal-contaminated wastewater is an important action to reduce The negative impacts of industrial wastes on water bodies. This work focuses on The application of a low-cost titanium (IV) phosphate sorbent of TiO(OH)H PO42H O chemical composition toward lead and zinc ions depen...
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| Veröffentlicht in: | International journal of molecular sciences 2020-01, Vol.21 (2), p.447 |
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| creator | Maslova, Marina V Ivanenko, Vladimir I Yanicheva, Nataliya Yu Mudruk, Natalia V |
| description | The treatment of heavy metal-contaminated wastewater is an important action to reduce The negative impacts of industrial wastes on water bodies. This work focuses on The application of a low-cost titanium (IV) phosphate sorbent of TiO(OH)H
PO42H
O chemical composition toward lead and zinc ions depending on their concentration and The temperature of The solution. The kinetic studies showed that The values of The rate of intraparticle diffusion and The effective diffusion coefficients for Zn
were considerably higher than those for Pb
. To explain The difference between The sorption kinetics rates for Pb
and Zn
, The effective radius and dehydration degree of The adsorbed ions were calculated. The sorbent capability of The lead and zinc ion removal and its excellent efficiency in The presence of a high concentration of calcium ions were demonstrated using simulated mine water. Due to The fast kinetics and The high exchange capacity of titanium phosphate toward divalent ions, this sorbent can be considered as a promising material for The concentration and immobilization of heavy metals into The phosphate matrix. |
| doi_str_mv | 10.3390/ijms21020447 |
| format | Article |
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PO42H
O chemical composition toward lead and zinc ions depending on their concentration and The temperature of The solution. The kinetic studies showed that The values of The rate of intraparticle diffusion and The effective diffusion coefficients for Zn
were considerably higher than those for Pb
. To explain The difference between The sorption kinetics rates for Pb
and Zn
, The effective radius and dehydration degree of The adsorbed ions were calculated. The sorbent capability of The lead and zinc ion removal and its excellent efficiency in The presence of a high concentration of calcium ions were demonstrated using simulated mine water. Due to The fast kinetics and The high exchange capacity of titanium phosphate toward divalent ions, this sorbent can be considered as a promising material for The concentration and immobilization of heavy metals into The phosphate matrix.</description><identifier>ISSN: 1422-0067</identifier><identifier>ISSN: 1661-6596</identifier><identifier>EISSN: 1422-0067</identifier><identifier>DOI: 10.3390/ijms21020447</identifier><identifier>PMID: 31936718</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Acids ; Calcium ; Calcium ions ; Chemical composition ; Chemical precipitation ; Dehydration ; Diffusion rate ; Heavy metals ; Hydration ; Immobilization ; Industrial wastes ; Ions ; Kinetics ; Lead ; Metals ; Mine waters ; NMR ; Nuclear magnetic resonance ; Phosphates ; Pollutants ; Sorbents ; Sorption ; Titanium ; Wastewater ; Water treatment ; Zinc</subject><ispartof>International journal of molecular sciences, 2020-01, Vol.21 (2), p.447</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 by the authors. 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-b65f1e5c1e42008c181406fc145af9cbe41004132cc1c4c3bc93b6f33bbc54513</citedby><cites>FETCH-LOGICAL-c412t-b65f1e5c1e42008c181406fc145af9cbe41004132cc1c4c3bc93b6f33bbc54513</cites><orcidid>0000-0003-1280-5554</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7013848/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7013848/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27923,27924,53790,53792</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31936718$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Maslova, Marina V</creatorcontrib><creatorcontrib>Ivanenko, Vladimir I</creatorcontrib><creatorcontrib>Yanicheva, Nataliya Yu</creatorcontrib><creatorcontrib>Mudruk, Natalia V</creatorcontrib><title>Comparison of The Sorption Kinetics of Lead(II) and Zinc(II) on Titanium Phosphate Ion-Exchanger</title><title>International journal of molecular sciences</title><addtitle>Int J Mol Sci</addtitle><description>The treatment of heavy metal-contaminated wastewater is an important action to reduce The negative impacts of industrial wastes on water bodies. This work focuses on The application of a low-cost titanium (IV) phosphate sorbent of TiO(OH)H
PO42H
O chemical composition toward lead and zinc ions depending on their concentration and The temperature of The solution. The kinetic studies showed that The values of The rate of intraparticle diffusion and The effective diffusion coefficients for Zn
were considerably higher than those for Pb
. To explain The difference between The sorption kinetics rates for Pb
and Zn
, The effective radius and dehydration degree of The adsorbed ions were calculated. The sorbent capability of The lead and zinc ion removal and its excellent efficiency in The presence of a high concentration of calcium ions were demonstrated using simulated mine water. Due to The fast kinetics and The high exchange capacity of titanium phosphate toward divalent ions, this sorbent can be considered as a promising material for The concentration and immobilization of heavy metals into The phosphate matrix.</description><subject>Acids</subject><subject>Calcium</subject><subject>Calcium ions</subject><subject>Chemical composition</subject><subject>Chemical precipitation</subject><subject>Dehydration</subject><subject>Diffusion rate</subject><subject>Heavy metals</subject><subject>Hydration</subject><subject>Immobilization</subject><subject>Industrial wastes</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Lead</subject><subject>Metals</subject><subject>Mine waters</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phosphates</subject><subject>Pollutants</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Titanium</subject><subject>Wastewater</subject><subject>Water treatment</subject><subject>Zinc</subject><issn>1422-0067</issn><issn>1661-6596</issn><issn>1422-0067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNpdkc1LxDAQxYMofqzePEvBi4LVTJJ224sgix-LCwquFy8xnU1tlm1Sk1b0v7d-snp685gfjxkeIbtAjznP6YmZ14EBZVSI4QrZBMFYTGk6XF2aN8hWCHNKGWdJvk42OOQ8HUK2SR5Hrm6UN8HZyJXRtNLRnfNNa3p_baxuDYaPxUSr2cF4fBgpO4sejMVP00NT0yprujq6rVxoKtXqaOxsfP6KlbJP2m-TtVItgt751gG5vzifjq7iyc3leHQ2iVEAa-MiTUrQCYIWjNIMIQNB0xJBJKrMsdACKBXAGSKgQF5gzou05LwoMBEJ8AE5_cptuqLWM9S29WohG29q5d-kU0b-3VhTySf3IocUeCayPuDgO8C7506HVtYmoF4slNWuC5JxnuVZznodkP1_6Nx13vbvSZaILGWcCtZTR18UeheC1-XvMUDlR3Vyuboe31t-4Bf-6Yq_A6a5k5s</recordid><startdate>20200110</startdate><enddate>20200110</enddate><creator>Maslova, Marina V</creator><creator>Ivanenko, Vladimir I</creator><creator>Yanicheva, Nataliya Yu</creator><creator>Mudruk, Natalia V</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-1280-5554</orcidid></search><sort><creationdate>20200110</creationdate><title>Comparison of The Sorption Kinetics of Lead(II) and Zinc(II) on Titanium Phosphate Ion-Exchanger</title><author>Maslova, Marina V ; Ivanenko, Vladimir I ; Yanicheva, Nataliya Yu ; Mudruk, Natalia V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-b65f1e5c1e42008c181406fc145af9cbe41004132cc1c4c3bc93b6f33bbc54513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acids</topic><topic>Calcium</topic><topic>Calcium ions</topic><topic>Chemical composition</topic><topic>Chemical precipitation</topic><topic>Dehydration</topic><topic>Diffusion rate</topic><topic>Heavy metals</topic><topic>Hydration</topic><topic>Immobilization</topic><topic>Industrial wastes</topic><topic>Ions</topic><topic>Kinetics</topic><topic>Lead</topic><topic>Metals</topic><topic>Mine waters</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phosphates</topic><topic>Pollutants</topic><topic>Sorbents</topic><topic>Sorption</topic><topic>Titanium</topic><topic>Wastewater</topic><topic>Water treatment</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maslova, Marina V</creatorcontrib><creatorcontrib>Ivanenko, Vladimir I</creatorcontrib><creatorcontrib>Yanicheva, Nataliya Yu</creatorcontrib><creatorcontrib>Mudruk, Natalia V</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Research Library (Corporate)</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>International journal of molecular sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maslova, Marina V</au><au>Ivanenko, Vladimir I</au><au>Yanicheva, Nataliya Yu</au><au>Mudruk, Natalia V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparison of The Sorption Kinetics of Lead(II) and Zinc(II) on Titanium Phosphate Ion-Exchanger</atitle><jtitle>International journal of molecular sciences</jtitle><addtitle>Int J Mol Sci</addtitle><date>2020-01-10</date><risdate>2020</risdate><volume>21</volume><issue>2</issue><spage>447</spage><pages>447-</pages><issn>1422-0067</issn><issn>1661-6596</issn><eissn>1422-0067</eissn><abstract>The treatment of heavy metal-contaminated wastewater is an important action to reduce The negative impacts of industrial wastes on water bodies. This work focuses on The application of a low-cost titanium (IV) phosphate sorbent of TiO(OH)H
PO42H
O chemical composition toward lead and zinc ions depending on their concentration and The temperature of The solution. The kinetic studies showed that The values of The rate of intraparticle diffusion and The effective diffusion coefficients for Zn
were considerably higher than those for Pb
. To explain The difference between The sorption kinetics rates for Pb
and Zn
, The effective radius and dehydration degree of The adsorbed ions were calculated. The sorbent capability of The lead and zinc ion removal and its excellent efficiency in The presence of a high concentration of calcium ions were demonstrated using simulated mine water. Due to The fast kinetics and The high exchange capacity of titanium phosphate toward divalent ions, this sorbent can be considered as a promising material for The concentration and immobilization of heavy metals into The phosphate matrix.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>31936718</pmid><doi>10.3390/ijms21020447</doi><orcidid>https://orcid.org/0000-0003-1280-5554</orcidid><oa>free_for_read</oa></addata></record> |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Acids Calcium Calcium ions Chemical composition Chemical precipitation Dehydration Diffusion rate Heavy metals Hydration Immobilization Industrial wastes Ions Kinetics Lead Metals Mine waters NMR Nuclear magnetic resonance Phosphates Pollutants Sorbents Sorption Titanium Wastewater Water treatment Zinc |
| title | Comparison of The Sorption Kinetics of Lead(II) and Zinc(II) on Titanium Phosphate Ion-Exchanger |
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