Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization
Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi MoO ) is performed. For this purpose, Bi MoO and La-doped Bi MoO were prepared by the sol-gel method. BiCl , Na MoO 2H O, and LaCl ·7H O were taken as the main precursors while...
Gespeichert in:
| Veröffentlicht in: | Materials 2019-12, Vol.13 (1), p.35 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 1 |
| container_start_page | 35 |
| container_title | Materials |
| container_volume | 13 |
| creator | Waqar, Muhammad Imran, Muhammad Adil, Syed Farooq Noreen, Sadia Latif, Shoomaila Khan, Mujeeb Siddiqui, Mohammed Rafiq H |
| description | Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi
MoO
) is performed. For this purpose, Bi
MoO
and La-doped Bi
MoO
were prepared by the sol-gel method. BiCl
, Na
MoO
2H
O, and LaCl
·7H
O were taken as the main precursors while sodium dodecyl sulfate was used as a surfactant. Both Bi
MoO
and La-doped Bi
MoO
were calcined at 650 °C for 2 h. These prepared materials were characterized by spectroscopic techniques such as UV-VIS, FT-IR, XRD, photoluminescence, XPS, along with other techniques such as SEM, TEM, TGA, etc. The investigation of luminescence behavior revealed that the La-doped Bi
MoO
nanocomposite exhibited much greater luminescence compared to the undoped Bi
MoO
. The photocatalytic behavior of the prepared materials was explored by studying the degradation of methylene blue (MB) at room temperature. The degradation of MB with Bi
MoO
and La-doped bismuth molybdate were observed to be 68% and 75% @ 45 s, respectively, indicating an enhancement of catalytic performance due to the La doping. |
| doi_str_mv | 10.3390/ma13010035 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6981540</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2548685185</sourcerecordid><originalsourceid>FETCH-LOGICAL-c472t-2cd6e9cf5215645a59ccb2d8d7bc8d7364bd6145149b6a92404625b27b8003563</originalsourceid><addsrcrecordid>eNpdUU1P3DAQtVArQJQLPwBF4lJVCvV3Yg6VYFk-pEXsoT1bjuMQoyTe2k6lRfx4zLJsF3zw2G_ePM3MA-AIwVNCBPzZK0QggpCwHbCPhOA5EpR-2XrvgcMQHmE6hKASi12wlyJHBSv3wfN0aNWgTZ3NWxddN_Z2MEGbBGVqWKNaRdUto9XZtGmstim7zFyTzVR-6Rap9sKGfoxtdue6ZVWraM6y2xiyuTcL5VW0bliJTdr009F4-7QCv4GvjeqCOVzHA_Dnavp7cpPP7q9vJ-ezXNMCxxzrmhuhG4YR45QpJrSucF3WRaXTRTitao4oQ1RUXAlMIeWYVbioyte9cHIAfr3pLsaqN3WaLnrVyYW3vfJL6ZSVHzODbeWD-ye5KBGjMAl8Xwt493c0IcrepiV1nRqMG4PEBIuCUM5Rop58oj660Q9pPIkZLXnJUMkS68cbS3sXgjfNphkE5auv8r-viXy83f6G-u4ieQFfrZ60</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2548685185</pqid></control><display><type>article</type><title>Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Waqar, Muhammad ; Imran, Muhammad ; Adil, Syed Farooq ; Noreen, Sadia ; Latif, Shoomaila ; Khan, Mujeeb ; Siddiqui, Mohammed Rafiq H</creator><creatorcontrib>Waqar, Muhammad ; Imran, Muhammad ; Adil, Syed Farooq ; Noreen, Sadia ; Latif, Shoomaila ; Khan, Mujeeb ; Siddiqui, Mohammed Rafiq H</creatorcontrib><description>Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi
MoO
) is performed. For this purpose, Bi
MoO
and La-doped Bi
MoO
were prepared by the sol-gel method. BiCl
, Na
MoO
2H
O, and LaCl
·7H
O were taken as the main precursors while sodium dodecyl sulfate was used as a surfactant. Both Bi
MoO
and La-doped Bi
MoO
were calcined at 650 °C for 2 h. These prepared materials were characterized by spectroscopic techniques such as UV-VIS, FT-IR, XRD, photoluminescence, XPS, along with other techniques such as SEM, TEM, TGA, etc. The investigation of luminescence behavior revealed that the La-doped Bi
MoO
nanocomposite exhibited much greater luminescence compared to the undoped Bi
MoO
. The photocatalytic behavior of the prepared materials was explored by studying the degradation of methylene blue (MB) at room temperature. The degradation of MB with Bi
MoO
and La-doped bismuth molybdate were observed to be 68% and 75% @ 45 s, respectively, indicating an enhancement of catalytic performance due to the La doping.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma13010035</identifier><identifier>PMID: 31861758</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Bismuth ; Chloride ; Degradation ; Dyes ; Efficiency ; Lanthanum chlorides ; Luminescence ; Metal oxides ; Methylene blue ; Morphology ; Nanocomposites ; Nanomaterials ; Particle size ; Photocatalysis ; Photoluminescence ; Room temperature ; Sodium ; Sodium dodecyl sulfate ; Sodium molybdate ; Sol-gel processes ; X ray photoelectron spectroscopy</subject><ispartof>Materials, 2019-12, Vol.13 (1), p.35</ispartof><rights>2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2019 by the authors. 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c472t-2cd6e9cf5215645a59ccb2d8d7bc8d7364bd6145149b6a92404625b27b8003563</citedby><cites>FETCH-LOGICAL-c472t-2cd6e9cf5215645a59ccb2d8d7bc8d7364bd6145149b6a92404625b27b8003563</cites><orcidid>0000-0002-2768-1235 ; 0000-0002-4703-0333 ; 0000-0002-4088-6913</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6981540/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6981540/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31861758$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Waqar, Muhammad</creatorcontrib><creatorcontrib>Imran, Muhammad</creatorcontrib><creatorcontrib>Adil, Syed Farooq</creatorcontrib><creatorcontrib>Noreen, Sadia</creatorcontrib><creatorcontrib>Latif, Shoomaila</creatorcontrib><creatorcontrib>Khan, Mujeeb</creatorcontrib><creatorcontrib>Siddiqui, Mohammed Rafiq H</creatorcontrib><title>Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi
MoO
) is performed. For this purpose, Bi
MoO
and La-doped Bi
MoO
were prepared by the sol-gel method. BiCl
, Na
MoO
2H
O, and LaCl
·7H
O were taken as the main precursors while sodium dodecyl sulfate was used as a surfactant. Both Bi
MoO
and La-doped Bi
MoO
were calcined at 650 °C for 2 h. These prepared materials were characterized by spectroscopic techniques such as UV-VIS, FT-IR, XRD, photoluminescence, XPS, along with other techniques such as SEM, TEM, TGA, etc. The investigation of luminescence behavior revealed that the La-doped Bi
MoO
nanocomposite exhibited much greater luminescence compared to the undoped Bi
MoO
. The photocatalytic behavior of the prepared materials was explored by studying the degradation of methylene blue (MB) at room temperature. The degradation of MB with Bi
MoO
and La-doped bismuth molybdate were observed to be 68% and 75% @ 45 s, respectively, indicating an enhancement of catalytic performance due to the La doping.</description><subject>Bismuth</subject><subject>Chloride</subject><subject>Degradation</subject><subject>Dyes</subject><subject>Efficiency</subject><subject>Lanthanum chlorides</subject><subject>Luminescence</subject><subject>Metal oxides</subject><subject>Methylene blue</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Particle size</subject><subject>Photocatalysis</subject><subject>Photoluminescence</subject><subject>Room temperature</subject><subject>Sodium</subject><subject>Sodium dodecyl sulfate</subject><subject>Sodium molybdate</subject><subject>Sol-gel processes</subject><subject>X ray photoelectron spectroscopy</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUU1P3DAQtVArQJQLPwBF4lJVCvV3Yg6VYFk-pEXsoT1bjuMQoyTe2k6lRfx4zLJsF3zw2G_ePM3MA-AIwVNCBPzZK0QggpCwHbCPhOA5EpR-2XrvgcMQHmE6hKASi12wlyJHBSv3wfN0aNWgTZ3NWxddN_Z2MEGbBGVqWKNaRdUto9XZtGmstim7zFyTzVR-6Rap9sKGfoxtdue6ZVWraM6y2xiyuTcL5VW0bliJTdr009F4-7QCv4GvjeqCOVzHA_Dnavp7cpPP7q9vJ-ezXNMCxxzrmhuhG4YR45QpJrSucF3WRaXTRTitao4oQ1RUXAlMIeWYVbioyte9cHIAfr3pLsaqN3WaLnrVyYW3vfJL6ZSVHzODbeWD-ye5KBGjMAl8Xwt493c0IcrepiV1nRqMG4PEBIuCUM5Rop58oj660Q9pPIkZLXnJUMkS68cbS3sXgjfNphkE5auv8r-viXy83f6G-u4ieQFfrZ60</recordid><startdate>20191220</startdate><enddate>20191220</enddate><creator>Waqar, Muhammad</creator><creator>Imran, Muhammad</creator><creator>Adil, Syed Farooq</creator><creator>Noreen, Sadia</creator><creator>Latif, Shoomaila</creator><creator>Khan, Mujeeb</creator><creator>Siddiqui, Mohammed Rafiq H</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-2768-1235</orcidid><orcidid>https://orcid.org/0000-0002-4703-0333</orcidid><orcidid>https://orcid.org/0000-0002-4088-6913</orcidid></search><sort><creationdate>20191220</creationdate><title>Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization</title><author>Waqar, Muhammad ; Imran, Muhammad ; Adil, Syed Farooq ; Noreen, Sadia ; Latif, Shoomaila ; Khan, Mujeeb ; Siddiqui, Mohammed Rafiq H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c472t-2cd6e9cf5215645a59ccb2d8d7bc8d7364bd6145149b6a92404625b27b8003563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Bismuth</topic><topic>Chloride</topic><topic>Degradation</topic><topic>Dyes</topic><topic>Efficiency</topic><topic>Lanthanum chlorides</topic><topic>Luminescence</topic><topic>Metal oxides</topic><topic>Methylene blue</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Particle size</topic><topic>Photocatalysis</topic><topic>Photoluminescence</topic><topic>Room temperature</topic><topic>Sodium</topic><topic>Sodium dodecyl sulfate</topic><topic>Sodium molybdate</topic><topic>Sol-gel processes</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Waqar, Muhammad</creatorcontrib><creatorcontrib>Imran, Muhammad</creatorcontrib><creatorcontrib>Adil, Syed Farooq</creatorcontrib><creatorcontrib>Noreen, Sadia</creatorcontrib><creatorcontrib>Latif, Shoomaila</creatorcontrib><creatorcontrib>Khan, Mujeeb</creatorcontrib><creatorcontrib>Siddiqui, Mohammed Rafiq H</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Waqar, Muhammad</au><au>Imran, Muhammad</au><au>Adil, Syed Farooq</au><au>Noreen, Sadia</au><au>Latif, Shoomaila</au><au>Khan, Mujeeb</au><au>Siddiqui, Mohammed Rafiq H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2019-12-20</date><risdate>2019</risdate><volume>13</volume><issue>1</issue><spage>35</spage><pages>35-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi
MoO
) is performed. For this purpose, Bi
MoO
and La-doped Bi
MoO
were prepared by the sol-gel method. BiCl
, Na
MoO
2H
O, and LaCl
·7H
O were taken as the main precursors while sodium dodecyl sulfate was used as a surfactant. Both Bi
MoO
and La-doped Bi
MoO
were calcined at 650 °C for 2 h. These prepared materials were characterized by spectroscopic techniques such as UV-VIS, FT-IR, XRD, photoluminescence, XPS, along with other techniques such as SEM, TEM, TGA, etc. The investigation of luminescence behavior revealed that the La-doped Bi
MoO
nanocomposite exhibited much greater luminescence compared to the undoped Bi
MoO
. The photocatalytic behavior of the prepared materials was explored by studying the degradation of methylene blue (MB) at room temperature. The degradation of MB with Bi
MoO
and La-doped bismuth molybdate were observed to be 68% and 75% @ 45 s, respectively, indicating an enhancement of catalytic performance due to the La doping.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>31861758</pmid><doi>10.3390/ma13010035</doi><orcidid>https://orcid.org/0000-0002-2768-1235</orcidid><orcidid>https://orcid.org/0000-0002-4703-0333</orcidid><orcidid>https://orcid.org/0000-0002-4088-6913</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2019-12, Vol.13 (1), p.35 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6981540 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Bismuth Chloride Degradation Dyes Efficiency Lanthanum chlorides Luminescence Metal oxides Methylene blue Morphology Nanocomposites Nanomaterials Particle size Photocatalysis Photoluminescence Room temperature Sodium Sodium dodecyl sulfate Sodium molybdate Sol-gel processes X ray photoelectron spectroscopy |
| title | Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T00%3A05%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhanced%20Photoluminescence%20and%20Photocatalytic%20Efficiency%20of%20La-Doped%20Bismuth%20Molybdate:%20Its%20Preparation%20and%20Characterization&rft.jtitle=Materials&rft.au=Waqar,%20Muhammad&rft.date=2019-12-20&rft.volume=13&rft.issue=1&rft.spage=35&rft.pages=35-&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma13010035&rft_dat=%3Cproquest_pubme%3E2548685185%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2548685185&rft_id=info:pmid/31861758&rfr_iscdi=true |