Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer–Moest Reaction under Flow Conditions

The highly strained cubane system is of great interest as a scaffold and rigid linker in both pharmaceutical and materials chemistry. The first electrochemical functionalisation of cubane by oxidative decarboxylative ether formation (Hofer–Moest reaction) was demonstrated. The mild conditions are co...

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Veröffentlicht in:	Chemistry : a European journal 2020-01, Vol.26 (2), p.374-378
Hauptverfasser:	Collin, Diego E., Folgueiras‐Amador, Ana A., Pletcher, Derek, Light, Mark E., Linclau, Bruno, Brown, Richard C. D.
Format:	Artikel
Sprache:	eng
Schlagworte:	bioisostere Carboxylic acids Chemistry Communication Communications Cubane cubanes Direct conversion Electrochemistry electrosynthesis flow electrochemistry Functional groups Organic chemistry oxidative decarboxylation
Online-Zugang:	Volltext
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