How to Control the Distribution of Anchored, Mn12–Stearate, Single-Molecule Magnets
Controlling the distribution of the Mn12–stearate, single-molecule magnets (SMMs) anchored on a select surface is expected to be a new method for tuning its interactions, and an investigation on the magnetic properties of separated magnetic molecules is also lacking. The anchoring of the SMMs at the...
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| Veröffentlicht in: | Nanomaterials (Basel, Switzerland) Switzerland), 2019-12, Vol.9 (12), p.1730 |
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| creator | Laskowska, Magdalena Pastukh, Oleksandr Kuźma, Dominika Laskowski, Łukasz |
| description | Controlling the distribution of the Mn12–stearate, single-molecule magnets (SMMs) anchored on a select surface is expected to be a new method for tuning its interactions, and an investigation on the magnetic properties of separated magnetic molecules is also lacking. The anchoring of the SMMs at the surface with an assumed statistic distance between each other is not an easy task; nevertheless, in this work, we show a synthesis which allows for this in detail. The immobilization of the Mn12–stearate was demonstrated with the use of FTO glasses and spherical silica as substrates. Based on differential pulse anodic stripping voltammetry (DPASV) and transmission electron microscopy (TEM) observations, we proved the efficiency of the method proposed. We observed continuous decreasing the number of bonds, and afterward, decreasing in the number of immobilized molecules with an increasing the number of spacer units used for separation of the magnetic particles. |
| doi_str_mv | 10.3390/nano9121730 |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Anodic stripping Communication Immobilization Magnetic properties Magnets Silica Silicon dioxide Substrates Transmission electron microscopy |
| title | How to Control the Distribution of Anchored, Mn12–Stearate, Single-Molecule Magnets |
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