Facile Synthesis of Triphenylamine Based Hyperbranched Polymer for Organic Field Effect Transistors
In this study, we reported the synthesis and characterization of a novel hyperbranched polymer (HBPs) [(4-phenyl)amino- -4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b']dithiophene (BDT) and triphenyleamine (TPA) constituent su...
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| Veröffentlicht in: | Nanomaterials (Basel, Switzerland) Switzerland), 2019-12, Vol.9 (12), p.1787 |
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| creator | Bathula, Chinna Appiagyei, Alfred Bekoe Yadav, Hemraj K, Ashok Kumar Ramesh, Sivalingam Shrestha, Nabeen K Shinde, Surendra Kim, Hyun-Seok Kim, Heung Soo Reddy, Lebaka Veeranjaneya Mohammed, Arifullah |
| description | In this study, we reported the synthesis and characterization of a novel hyperbranched polymer (HBPs)
[(4-phenyl)amino-
-4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b']dithiophene (BDT) and triphenyleamine (TPA) constituent subunits by A
+ B
type Stille's reaction. An estimated optical band gap of 1.69 eV with HOMO and LUMO levels of -5.29 eV and -3.60 eV, respectively, as well as a high thermal stability up to 398 °C were characterized for the synthesized polymer. PTPABDT fabricated as an encapsulated top gate/bottom contact (TGBC), organic field effect transistors (OFET) exhibited a p-type behavior with maximum field-effect mobility (µmax) and an on/off ratio of 1.22 × 10
cm
V
s
and 7.47 × 10
, respectively. |
| doi_str_mv | 10.3390/nano9121787 |
| format | Article |
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[(4-phenyl)amino-
-4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b']dithiophene (BDT) and triphenyleamine (TPA) constituent subunits by A
+ B
type Stille's reaction. An estimated optical band gap of 1.69 eV with HOMO and LUMO levels of -5.29 eV and -3.60 eV, respectively, as well as a high thermal stability up to 398 °C were characterized for the synthesized polymer. PTPABDT fabricated as an encapsulated top gate/bottom contact (TGBC), organic field effect transistors (OFET) exhibited a p-type behavior with maximum field-effect mobility (µmax) and an on/off ratio of 1.22 × 10
cm
V
s
and 7.47 × 10
, respectively.</description><identifier>ISSN: 2079-4991</identifier><identifier>EISSN: 2079-4991</identifier><identifier>DOI: 10.3390/nano9121787</identifier><identifier>PMID: 31888164</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Chemical synthesis ; Communication ; Electrodes ; Field effect transistors ; Glass substrates ; Molecular orbitals ; NMR ; Nuclear magnetic resonance ; Organic light emitting diodes ; Polymerization ; Polymers ; Semiconductor devices ; Thermal stability ; Transistors</subject><ispartof>Nanomaterials (Basel, Switzerland), 2019-12, Vol.9 (12), p.1787</ispartof><rights>2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2019 by the authors. 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-7b5f3d78106df9855e45ac1e4de776df813459f7b1d98301b6a7ecad49d111b33</citedby><cites>FETCH-LOGICAL-c409t-7b5f3d78106df9855e45ac1e4de776df813459f7b1d98301b6a7ecad49d111b33</cites><orcidid>0000-0003-1127-5766 ; 0000-0001-7793-8134 ; 0000-0001-8089-5219 ; 0000-0001-7057-5174</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6955725/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6955725/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31888164$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bathula, Chinna</creatorcontrib><creatorcontrib>Appiagyei, Alfred Bekoe</creatorcontrib><creatorcontrib>Yadav, Hemraj</creatorcontrib><creatorcontrib>K, Ashok Kumar</creatorcontrib><creatorcontrib>Ramesh, Sivalingam</creatorcontrib><creatorcontrib>Shrestha, Nabeen K</creatorcontrib><creatorcontrib>Shinde, Surendra</creatorcontrib><creatorcontrib>Kim, Hyun-Seok</creatorcontrib><creatorcontrib>Kim, Heung Soo</creatorcontrib><creatorcontrib>Reddy, Lebaka Veeranjaneya</creatorcontrib><creatorcontrib>Mohammed, Arifullah</creatorcontrib><title>Facile Synthesis of Triphenylamine Based Hyperbranched Polymer for Organic Field Effect Transistors</title><title>Nanomaterials (Basel, Switzerland)</title><addtitle>Nanomaterials (Basel)</addtitle><description>In this study, we reported the synthesis and characterization of a novel hyperbranched polymer (HBPs)
[(4-phenyl)amino-
-4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b']dithiophene (BDT) and triphenyleamine (TPA) constituent subunits by A
+ B
type Stille's reaction. An estimated optical band gap of 1.69 eV with HOMO and LUMO levels of -5.29 eV and -3.60 eV, respectively, as well as a high thermal stability up to 398 °C were characterized for the synthesized polymer. PTPABDT fabricated as an encapsulated top gate/bottom contact (TGBC), organic field effect transistors (OFET) exhibited a p-type behavior with maximum field-effect mobility (µmax) and an on/off ratio of 1.22 × 10
cm
V
s
and 7.47 × 10
, respectively.</description><subject>Chemical synthesis</subject><subject>Communication</subject><subject>Electrodes</subject><subject>Field effect transistors</subject><subject>Glass substrates</subject><subject>Molecular orbitals</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic light emitting diodes</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Semiconductor devices</subject><subject>Thermal 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Heung Soo</au><au>Reddy, Lebaka Veeranjaneya</au><au>Mohammed, Arifullah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile Synthesis of Triphenylamine Based Hyperbranched Polymer for Organic Field Effect Transistors</atitle><jtitle>Nanomaterials (Basel, Switzerland)</jtitle><addtitle>Nanomaterials (Basel)</addtitle><date>2019-12-16</date><risdate>2019</risdate><volume>9</volume><issue>12</issue><spage>1787</spage><pages>1787-</pages><issn>2079-4991</issn><eissn>2079-4991</eissn><abstract>In this study, we reported the synthesis and characterization of a novel hyperbranched polymer (HBPs)
[(4-phenyl)amino-
-4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene] (PTPABDT) composed of benzo[1,2-b:4,5-b']dithiophene (BDT) and triphenyleamine (TPA) constituent subunits by A
+ B
type Stille's reaction. An estimated optical band gap of 1.69 eV with HOMO and LUMO levels of -5.29 eV and -3.60 eV, respectively, as well as a high thermal stability up to 398 °C were characterized for the synthesized polymer. PTPABDT fabricated as an encapsulated top gate/bottom contact (TGBC), organic field effect transistors (OFET) exhibited a p-type behavior with maximum field-effect mobility (µmax) and an on/off ratio of 1.22 × 10
cm
V
s
and 7.47 × 10
, respectively.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>31888164</pmid><doi>10.3390/nano9121787</doi><orcidid>https://orcid.org/0000-0003-1127-5766</orcidid><orcidid>https://orcid.org/0000-0001-7793-8134</orcidid><orcidid>https://orcid.org/0000-0001-8089-5219</orcidid><orcidid>https://orcid.org/0000-0001-7057-5174</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Chemical synthesis Communication Electrodes Field effect transistors Glass substrates Molecular orbitals NMR Nuclear magnetic resonance Organic light emitting diodes Polymerization Polymers Semiconductor devices Thermal stability Transistors |
| title | Facile Synthesis of Triphenylamine Based Hyperbranched Polymer for Organic Field Effect Transistors |
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