Geometric and electronic structure of a crystallographically characterized thiolate-ligated binuclear peroxo-bridged cobalt(III) complex

In order to shed light on metal-dependent mechanisms for O–O bond cleavage, and its microscopic reverse, we compare herein the electronic and geometric structures of O 2 -derived binuclear Co(III)– and Mn(III)–peroxo compounds. Binuclear metal peroxo complexes are proposed to form as intermediates d...

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