Fabrication of ZnO nanoparticles adorned nitrogen-doped carbon balls and their application in photodegradation of organic dyes
In the present study, a novel ZnO nanoparticles adorned nitrogen-doped carbon balls (ZnO@CBs) were successfully synthesized from polybenzoxazine and ZnO nanoparticles through a simple carbonization method. The typical wurtzite hexagonal zinc oxide phase in ZnO@CBs and degree of graphitization were r...
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| Veröffentlicht in: | Scientific reports 2019-12, Vol.9 (1), p.19509-13, Article 19509 |
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| description | In the present study, a novel ZnO nanoparticles adorned nitrogen-doped carbon balls (ZnO@CBs) were successfully synthesized from polybenzoxazine and ZnO nanoparticles through a simple carbonization method. The typical wurtzite hexagonal zinc oxide phase in ZnO@CBs and degree of graphitization were revealed by the X-ray diffraction pattern. The field emission scanning electron microscopy confirmed that the synthesized carbon materials have well dispersed ball-like structure, wherein, the ZnO nanoparticles are distributed evenly on the carbon balls (CBs). The synthesized ZnO@CBs with different wt.% (20, 40, 60 and 80) and bare ZnO nanoparticles were investigated for methylene blue (MB) dye degradation experiment. The synthesized ZnO@CBs exhibited high activity in the degradation of MB. Among the different wt.% of ZnO@CBs, 60 wt.% of ZnO@CBs showed the highest MB degradation ratio (99%) with a fast degradation rate (1.65% min
−1
) under the following optimum conditions: 20 mg of ZnO@CBs in 50 mL of MB solution at room temperature. |
| doi_str_mv | 10.1038/s41598-019-56109-3 |
| format | Article |
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−1
) under the following optimum conditions: 20 mg of ZnO@CBs in 50 mL of MB solution at room temperature.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-019-56109-3</identifier><identifier>PMID: 31863017</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>140/131 ; 140/133 ; 140/146 ; 639/638 ; 639/638/455/957 ; 639/638/455/958 ; Carbon ; Dyes ; Fabrication ; Humanities and Social Sciences ; Methylene blue ; multidisciplinary ; Nanoparticles ; Nitrogen ; Photodegradation ; Scanning electron microscopy ; Science ; Science (multidisciplinary) ; X-ray diffraction ; Zinc oxide ; Zinc oxides</subject><ispartof>Scientific reports, 2019-12, Vol.9 (1), p.19509-13, Article 19509</ispartof><rights>The Author(s) 2019</rights><rights>2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c474t-57894c92c713953dd4d2a263038dc377b401883a4164b894d3f44e79507b64ce3</citedby><cites>FETCH-LOGICAL-c474t-57894c92c713953dd4d2a263038dc377b401883a4164b894d3f44e79507b64ce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6925138/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6925138/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,41120,42189,51576,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31863017$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Thirukumaran, Periyasamy</creatorcontrib><creatorcontrib>Atchudan, Raji</creatorcontrib><creatorcontrib>Parveen, Asrafali Shakila</creatorcontrib><creatorcontrib>Kalaiarasan, Koteeswaran</creatorcontrib><creatorcontrib>Lee, Yong Rok</creatorcontrib><creatorcontrib>Kim, Seong-Cheol</creatorcontrib><title>Fabrication of ZnO nanoparticles adorned nitrogen-doped carbon balls and their application in photodegradation of organic dyes</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>In the present study, a novel ZnO nanoparticles adorned nitrogen-doped carbon balls (ZnO@CBs) were successfully synthesized from polybenzoxazine and ZnO nanoparticles through a simple carbonization method. The typical wurtzite hexagonal zinc oxide phase in ZnO@CBs and degree of graphitization were revealed by the X-ray diffraction pattern. The field emission scanning electron microscopy confirmed that the synthesized carbon materials have well dispersed ball-like structure, wherein, the ZnO nanoparticles are distributed evenly on the carbon balls (CBs). The synthesized ZnO@CBs with different wt.% (20, 40, 60 and 80) and bare ZnO nanoparticles were investigated for methylene blue (MB) dye degradation experiment. The synthesized ZnO@CBs exhibited high activity in the degradation of MB. Among the different wt.% of ZnO@CBs, 60 wt.% of ZnO@CBs showed the highest MB degradation ratio (99%) with a fast degradation rate (1.65% min
−1
) under the following optimum conditions: 20 mg of ZnO@CBs in 50 mL of MB solution at room temperature.</description><subject>140/131</subject><subject>140/133</subject><subject>140/146</subject><subject>639/638</subject><subject>639/638/455/957</subject><subject>639/638/455/958</subject><subject>Carbon</subject><subject>Dyes</subject><subject>Fabrication</subject><subject>Humanities and Social Sciences</subject><subject>Methylene blue</subject><subject>multidisciplinary</subject><subject>Nanoparticles</subject><subject>Nitrogen</subject><subject>Photodegradation</subject><subject>Scanning electron microscopy</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>X-ray diffraction</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kUFvFSEUhYnR2Kb2D7gwJG7cTAUuMwwbE9NYa9Kkm3bTDbkDvHk082CEeSbd-Nulfe2zuigbIPe753I4hLzn7IQz6D8XyVvdN4zrpu040w28IoeCybYRIMTrZ-cDclzKLaurFVpy_ZYcAO87YFwdkt9nOORgcQkp0rSiN_GSRoxpxrwEO_lC0aUcvaMxLDmNPjYuzfVqMQ-1ZcBpqkx0dFn7kCnO8_QkFyKd12lJzo8Z3X5EyiPGYKm78-UdebPCqfjjx_2IXJ99uzo9by4uv_84_XrRWKnk0rSq19JqYRUH3YJz0gkU1QL0zoJSg2S87wEl7-RQUQcrKb3SLVNDJ62HI_Jlpztvh4131scl42TmHDaY70zCYP6txLA2Y_plOi1aDn0V-PQokNPPrS-L2YRi_TRh9GlbTP1orYDzTlX043_obdrmWO09UCA6JqFSYkfZnErJfrV_DGfmPmGzS9jUhM1Dwua-6cNzG_uWpzwrADug1FIcff47-wXZP5mBsps</recordid><startdate>20191220</startdate><enddate>20191220</enddate><creator>Thirukumaran, Periyasamy</creator><creator>Atchudan, Raji</creator><creator>Parveen, Asrafali Shakila</creator><creator>Kalaiarasan, Koteeswaran</creator><creator>Lee, Yong Rok</creator><creator>Kim, Seong-Cheol</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20191220</creationdate><title>Fabrication of ZnO nanoparticles adorned nitrogen-doped carbon balls and their application in photodegradation of organic dyes</title><author>Thirukumaran, Periyasamy ; Atchudan, Raji ; Parveen, Asrafali Shakila ; Kalaiarasan, Koteeswaran ; Lee, Yong Rok ; Kim, Seong-Cheol</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c474t-57894c92c713953dd4d2a263038dc377b401883a4164b894d3f44e79507b64ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>140/131</topic><topic>140/133</topic><topic>140/146</topic><topic>639/638</topic><topic>639/638/455/957</topic><topic>639/638/455/958</topic><topic>Carbon</topic><topic>Dyes</topic><topic>Fabrication</topic><topic>Humanities and Social Sciences</topic><topic>Methylene blue</topic><topic>multidisciplinary</topic><topic>Nanoparticles</topic><topic>Nitrogen</topic><topic>Photodegradation</topic><topic>Scanning electron microscopy</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>X-ray diffraction</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thirukumaran, Periyasamy</creatorcontrib><creatorcontrib>Atchudan, Raji</creatorcontrib><creatorcontrib>Parveen, Asrafali Shakila</creatorcontrib><creatorcontrib>Kalaiarasan, Koteeswaran</creatorcontrib><creatorcontrib>Lee, Yong Rok</creatorcontrib><creatorcontrib>Kim, Seong-Cheol</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thirukumaran, Periyasamy</au><au>Atchudan, Raji</au><au>Parveen, Asrafali Shakila</au><au>Kalaiarasan, Koteeswaran</au><au>Lee, Yong Rok</au><au>Kim, Seong-Cheol</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of ZnO nanoparticles adorned nitrogen-doped carbon balls and their application in photodegradation of organic dyes</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2019-12-20</date><risdate>2019</risdate><volume>9</volume><issue>1</issue><spage>19509</spage><epage>13</epage><pages>19509-13</pages><artnum>19509</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>In the present study, a novel ZnO nanoparticles adorned nitrogen-doped carbon balls (ZnO@CBs) were successfully synthesized from polybenzoxazine and ZnO nanoparticles through a simple carbonization method. The typical wurtzite hexagonal zinc oxide phase in ZnO@CBs and degree of graphitization were revealed by the X-ray diffraction pattern. The field emission scanning electron microscopy confirmed that the synthesized carbon materials have well dispersed ball-like structure, wherein, the ZnO nanoparticles are distributed evenly on the carbon balls (CBs). The synthesized ZnO@CBs with different wt.% (20, 40, 60 and 80) and bare ZnO nanoparticles were investigated for methylene blue (MB) dye degradation experiment. The synthesized ZnO@CBs exhibited high activity in the degradation of MB. Among the different wt.% of ZnO@CBs, 60 wt.% of ZnO@CBs showed the highest MB degradation ratio (99%) with a fast degradation rate (1.65% min
−1
) under the following optimum conditions: 20 mg of ZnO@CBs in 50 mL of MB solution at room temperature.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>31863017</pmid><doi>10.1038/s41598-019-56109-3</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 140/131 140/133 140/146 639/638 639/638/455/957 639/638/455/958 Carbon Dyes Fabrication Humanities and Social Sciences Methylene blue multidisciplinary Nanoparticles Nitrogen Photodegradation Scanning electron microscopy Science Science (multidisciplinary) X-ray diffraction Zinc oxide Zinc oxides |
| title | Fabrication of ZnO nanoparticles adorned nitrogen-doped carbon balls and their application in photodegradation of organic dyes |
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