1,2-Bis(arylthio)arene synthesis via aryne intermediates

Lithium 1,1-diadamantylamide (LDAM) base-promoted insertion of arynes into disulfide S-S bonds is described. After generation of arynes from readily available aryl halides and triflates, reactions with diaryl and diisopropyl disulfides afford the insertion products in moderate to excellent yields. U...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-08, Vol.55 (64), p.9467-9470
Hauptverfasser:	Mesgar, Milad, Nguyen-Le, Justin, Daugulis, Olafs
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds aromatic hydrocarbons chemical bonding chemical reactions Cyclohexene cyclohexenes disulfides Halides Insertion Lithium organic halogen compounds organic sulfur compounds
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!