Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

A substrate-directed enantioselective anti-carboboration reaction of alkenes has been developed, wherein a carbon-based nucleophile and a boron moiety are installed across the CC bond through a five-membered palladacycle intermediate. A preliminary result also shows it is possible to extend this re...

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Veröffentlicht in:	ACS catalysis 2019-04, Vol.9 (4), p.3260-3265
Hauptverfasser:	Liu, Zhen, Li, Xiaohan, Zeng, Tian, Engle, Keary M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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