Urethane Formation with an Excess of Isocyanate or Alcohol: Experimental and Ab Initio Study

A kinetic and mechanistic investigation of the alcoholysis of phenyl isocyanate using 1-propanol as the alcohol was undertaken. A molecular mechanism of urethane formation in both alcohol and isocyanate excess is explored using a combination of an accurate fourth generation Gaussian thermochemistry...

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Veröffentlicht in:	Polymers 2019-09, Vol.11 (10), p.1543
Hauptverfasser:	Cheikh, Wafaa, Rózsa, Zsófia Borbála, Camacho López, Christian Orlando, Mizsey, Péter, Viskolcz, Béla, Szőri, Milán, Fejes, Zsolt
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Alcohol Catalysis Energy Experiments Isocyanates Solvents Thermochemistry
Online-Zugang:	Volltext
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