Synthesis of Magnesium- and Silicon-modified Hydroxyapatites by Microwave-Assisted Method
Nanopowders of hydroxyapatite (HA), modified by magnesium (MgHA) and by silicon (SiHA) were obtained by liquid-phase microwave synthesis method. X-ray diffraction and IR spectroscopy results showed that Mg 2+ and SiO 4 4− ions were present in the synthesized products both as secondary phases and as...
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| Veröffentlicht in: | Scientific reports 2019-10, Vol.9 (1), p.14836-10, Article 14836 |
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| creator | Rasskazova, Liudmila A. Zhuk, Ilya V. Korotchenko, Natalia M. Brichkov, Anton S. Chen, Yu-Wen Paukshtis, Evgeniy A. Ivanov, Vladimir K. Kurzina, Irina A. Kozik, Vladimir V. |
| description | Nanopowders of hydroxyapatite (HA), modified by magnesium (MgHA) and by silicon (SiHA) were obtained by liquid-phase microwave synthesis method. X-ray diffraction and IR spectroscopy results showed that Mg
2+
and SiO
4
4−
ions were present in the synthesized products both as secondary phases and as part of the HA phase. Whitlockite was found in the magnesium-modified HA (MgHA) and larnite was found in the silicon-modified HA (SiHA); ion substitution for both materials resulted in solid solutions. In the synthesized samples of modified HA, the increase of particle size of powders was in the order HA HA. The rates of calcium phosphate layer deposition on the surface of these materials at 37 °C in the model simulated body fluid solution showed similar dependence. |
| doi_str_mv | 10.1038/s41598-019-50777-x |
| format | Article |
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2+
and SiO
4
4−
ions were present in the synthesized products both as secondary phases and as part of the HA phase. Whitlockite was found in the magnesium-modified HA (MgHA) and larnite was found in the silicon-modified HA (SiHA); ion substitution for both materials resulted in solid solutions. In the synthesized samples of modified HA, the increase of particle size of powders was in the order HA < SiHA < MgHA, which was calculated through data specific surface area and measured pycnometric density of the powders. The Lewis acid sites (Ca
2+
, Mg
2+
, Si
4+
) were present using spectral probes on the surface of the samples of HA, MgHA, and SiHA, and the acidity of these sites decreased in the order SiHA > MgHA > HA. The rates of calcium phosphate layer deposition on the surface of these materials at 37 °C in the model simulated body fluid solution showed similar dependence.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-019-50777-x</identifier><identifier>PMID: 31619688</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>631/1647 ; 631/57/2272 ; 631/92 ; Acidity ; Bones ; Calcium phosphates ; Composite materials ; Humanities and Social Sciences ; Hydroxyapatite ; Infrared spectroscopy ; Magnesium ; Morphology ; multidisciplinary ; Nitrates ; Polyethylene ; Polyglycolic acid ; Science ; Science (multidisciplinary) ; Silicon ; Transplants & implants ; X-ray diffraction</subject><ispartof>Scientific reports, 2019-10, Vol.9 (1), p.14836-10, Article 14836</ispartof><rights>The Author(s) 2019</rights><rights>2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c474t-8a50d8ce6f9a389aad943361168f22c55cd11c81cc69fd65ab3417f4acbf7a1d3</citedby><cites>FETCH-LOGICAL-c474t-8a50d8ce6f9a389aad943361168f22c55cd11c81cc69fd65ab3417f4acbf7a1d3</cites><orcidid>0000-0003-4976-2295 ; 0000-0002-8519-2595</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6795999/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6795999/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,41120,42189,51576,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31619688$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rasskazova, Liudmila A.</creatorcontrib><creatorcontrib>Zhuk, Ilya V.</creatorcontrib><creatorcontrib>Korotchenko, Natalia M.</creatorcontrib><creatorcontrib>Brichkov, Anton S.</creatorcontrib><creatorcontrib>Chen, Yu-Wen</creatorcontrib><creatorcontrib>Paukshtis, Evgeniy A.</creatorcontrib><creatorcontrib>Ivanov, Vladimir K.</creatorcontrib><creatorcontrib>Kurzina, Irina A.</creatorcontrib><creatorcontrib>Kozik, Vladimir V.</creatorcontrib><title>Synthesis of Magnesium- and Silicon-modified Hydroxyapatites by Microwave-Assisted Method</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Nanopowders of hydroxyapatite (HA), modified by magnesium (MgHA) and by silicon (SiHA) were obtained by liquid-phase microwave synthesis method. X-ray diffraction and IR spectroscopy results showed that Mg
2+
and SiO
4
4−
ions were present in the synthesized products both as secondary phases and as part of the HA phase. Whitlockite was found in the magnesium-modified HA (MgHA) and larnite was found in the silicon-modified HA (SiHA); ion substitution for both materials resulted in solid solutions. In the synthesized samples of modified HA, the increase of particle size of powders was in the order HA < SiHA < MgHA, which was calculated through data specific surface area and measured pycnometric density of the powders. The Lewis acid sites (Ca
2+
, Mg
2+
, Si
4+
) were present using spectral probes on the surface of the samples of HA, MgHA, and SiHA, and the acidity of these sites decreased in the order SiHA > MgHA > HA. The rates of calcium phosphate layer deposition on the surface of these materials at 37 °C in the model simulated body fluid solution showed similar dependence.</description><subject>631/1647</subject><subject>631/57/2272</subject><subject>631/92</subject><subject>Acidity</subject><subject>Bones</subject><subject>Calcium phosphates</subject><subject>Composite materials</subject><subject>Humanities and Social Sciences</subject><subject>Hydroxyapatite</subject><subject>Infrared spectroscopy</subject><subject>Magnesium</subject><subject>Morphology</subject><subject>multidisciplinary</subject><subject>Nitrates</subject><subject>Polyethylene</subject><subject>Polyglycolic acid</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Silicon</subject><subject>Transplants & implants</subject><subject>X-ray diffraction</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kT1vFDEQhi0EIlHIH6BAK9HQGPy9doMURYEg5UQRKKgsnz_uHO3ah70bbv89JhdCoGCaGWmeecfjF4CXGL3FiMp3lWGuJERYQY76vof7J-CYIMYhoYQ8fVQfgdNab1ALThTD6jk4olhgJaQ8Bt-ulzRtfY21y6FbmU1q9TzCziTXXcch2pzgmF0M0bvucnEl7xezM1OcfO3WS7eKtuQf5tbDs9pUpkat_LTN7gV4FsxQ_el9PgFfP1x8Ob-EV58_fjo_u4KW9WyC0nDkpPUiKEOlMsYpRqnAWMhAiOXcOoytxNYKFZzgZk0Z7gMzdh16gx09Ae8Purt5PXpnfZqKGfSuxNGURWcT9d-dFLd6k2-16BVXSjWBN_cCJX-ffZ30GKv1w2CSz3PVhCLBFMICNfT1P-hNnktq591RBGGsZKPIgWo_U2vx4eExGOlf5umDebqZp-_M0_s29OrxGQ8jv61qAD0AtbXSxpc_u_8j-xM_rKdb</recordid><startdate>20191016</startdate><enddate>20191016</enddate><creator>Rasskazova, Liudmila A.</creator><creator>Zhuk, Ilya V.</creator><creator>Korotchenko, Natalia M.</creator><creator>Brichkov, Anton S.</creator><creator>Chen, Yu-Wen</creator><creator>Paukshtis, Evgeniy A.</creator><creator>Ivanov, Vladimir K.</creator><creator>Kurzina, Irina A.</creator><creator>Kozik, Vladimir V.</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-4976-2295</orcidid><orcidid>https://orcid.org/0000-0002-8519-2595</orcidid></search><sort><creationdate>20191016</creationdate><title>Synthesis of Magnesium- and Silicon-modified Hydroxyapatites by Microwave-Assisted Method</title><author>Rasskazova, Liudmila A. ; Zhuk, Ilya V. ; Korotchenko, Natalia M. ; Brichkov, Anton S. ; Chen, Yu-Wen ; Paukshtis, Evgeniy A. ; Ivanov, Vladimir K. ; Kurzina, Irina A. ; Kozik, Vladimir V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c474t-8a50d8ce6f9a389aad943361168f22c55cd11c81cc69fd65ab3417f4acbf7a1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>631/1647</topic><topic>631/57/2272</topic><topic>631/92</topic><topic>Acidity</topic><topic>Bones</topic><topic>Calcium phosphates</topic><topic>Composite materials</topic><topic>Humanities and Social Sciences</topic><topic>Hydroxyapatite</topic><topic>Infrared spectroscopy</topic><topic>Magnesium</topic><topic>Morphology</topic><topic>multidisciplinary</topic><topic>Nitrates</topic><topic>Polyethylene</topic><topic>Polyglycolic acid</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Silicon</topic><topic>Transplants & implants</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rasskazova, Liudmila A.</creatorcontrib><creatorcontrib>Zhuk, Ilya V.</creatorcontrib><creatorcontrib>Korotchenko, Natalia M.</creatorcontrib><creatorcontrib>Brichkov, Anton S.</creatorcontrib><creatorcontrib>Chen, Yu-Wen</creatorcontrib><creatorcontrib>Paukshtis, Evgeniy A.</creatorcontrib><creatorcontrib>Ivanov, Vladimir K.</creatorcontrib><creatorcontrib>Kurzina, Irina A.</creatorcontrib><creatorcontrib>Kozik, Vladimir V.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rasskazova, Liudmila A.</au><au>Zhuk, Ilya V.</au><au>Korotchenko, Natalia M.</au><au>Brichkov, Anton S.</au><au>Chen, Yu-Wen</au><au>Paukshtis, Evgeniy A.</au><au>Ivanov, Vladimir K.</au><au>Kurzina, Irina A.</au><au>Kozik, Vladimir V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Magnesium- and Silicon-modified Hydroxyapatites by Microwave-Assisted Method</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2019-10-16</date><risdate>2019</risdate><volume>9</volume><issue>1</issue><spage>14836</spage><epage>10</epage><pages>14836-10</pages><artnum>14836</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Nanopowders of hydroxyapatite (HA), modified by magnesium (MgHA) and by silicon (SiHA) were obtained by liquid-phase microwave synthesis method. X-ray diffraction and IR spectroscopy results showed that Mg
2+
and SiO
4
4−
ions were present in the synthesized products both as secondary phases and as part of the HA phase. Whitlockite was found in the magnesium-modified HA (MgHA) and larnite was found in the silicon-modified HA (SiHA); ion substitution for both materials resulted in solid solutions. In the synthesized samples of modified HA, the increase of particle size of powders was in the order HA < SiHA < MgHA, which was calculated through data specific surface area and measured pycnometric density of the powders. The Lewis acid sites (Ca
2+
, Mg
2+
, Si
4+
) were present using spectral probes on the surface of the samples of HA, MgHA, and SiHA, and the acidity of these sites decreased in the order SiHA > MgHA > HA. The rates of calcium phosphate layer deposition on the surface of these materials at 37 °C in the model simulated body fluid solution showed similar dependence.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>31619688</pmid><doi>10.1038/s41598-019-50777-x</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-4976-2295</orcidid><orcidid>https://orcid.org/0000-0002-8519-2595</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | 631/1647 631/57/2272 631/92 Acidity Bones Calcium phosphates Composite materials Humanities and Social Sciences Hydroxyapatite Infrared spectroscopy Magnesium Morphology multidisciplinary Nitrates Polyethylene Polyglycolic acid Science Science (multidisciplinary) Silicon Transplants & implants X-ray diffraction |
| title | Synthesis of Magnesium- and Silicon-modified Hydroxyapatites by Microwave-Assisted Method |
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