Nickel‐Catalyzed Stereodivergent Synthesis of E‐ and Z‐Alkenes by Hydrogenation of Alkynes

A convenient protocol for stereodivergent hydrogenation of alkynes to E‐ and Z‐alkenes by using nickel catalysts was developed. Simple Ni(NO3)2⋅6 H2O as a catalyst precursor formed active nanoparticles, which were effective for the semihydrogenation of several alkynes with high selectivity for the Z...

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Veröffentlicht in:	ChemSusChem 2019-07, Vol.12 (14), p.3363-3369
Hauptverfasser:	Murugesan, Kathiravan, Bheeter, Charles Beromeo, Linnebank, Pim R., Spannenberg, Anke, Reek, Joost N. H., Jagadeesh, Rajenahally V., Beller, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkynes Catalysis Catalysts Chemical synthesis Density functional theory Hydrogenation Nanoparticles Nickel Selectivity stereoselectivity
Online-Zugang:	Volltext
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