A Molecular Torsion Balance Study: A Nearby Anionic Group Exerts Little Influence on Hydrophobic Interactions between Nonpolar Surfaces
Polar groups have a solvent ordering effect on water and therefore may affect hydrophobic binding energies for nearby lipophilic surfaces. This would mean that determinations of excess surface free energy association energies require consideration of nearby polar functional groups. This paper report...
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| Veröffentlicht in: | Chemistry : a European journal 2019-11, Vol.25 (61), p.14010-14014 |
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| container_title | Chemistry : a European journal |
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| creator | Ling, Xiujun Wilcox, Craig S. |
| description | Polar groups have a solvent ordering effect on water and therefore may affect hydrophobic binding energies for nearby lipophilic surfaces. This would mean that determinations of excess surface free energy association energies require consideration of nearby polar functional groups. This paper reports results of a study to measure this possible effect. It was concluded from the models used here that an anionic polar group nearby a hydrophobic surface has little or no effect on the magnitude of hydrophobic association.
Polar groups: This paper reports results of a study to measure any effect of polar groups on hydrophobic binding energies for nearby lipophilic surfaces. It was concluded from the models used here that an anionic polar group nearby a hydrophobic surface has little or no effect on the magnitude of hydrophobic association. |
| doi_str_mv | 10.1002/chem.201901208 |
| format | Article |
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| ispartof | Chemistry : a European journal, 2019-11, Vol.25 (61), p.14010-14014 |
| issn | 0947-6539 1521-3765 1521-3765 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Balances (scales) Chemistry Free energy Functional groups hydrophobic interaction Hydrophobicity Lipophilic lipophilicity non-covalent interactions polarity protein folding |
| title | A Molecular Torsion Balance Study: A Nearby Anionic Group Exerts Little Influence on Hydrophobic Interactions between Nonpolar Surfaces |
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