Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-Derived Amphiphiles in Water

Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-Derived Amphiphiles in Water

The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple son...

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Veröffentlicht in:Langmuir 2019-09, Vol.35 (36), p.11821-11828
Hauptverfasser: Tosi, Filippo, Stuart, Marc C. A, Smit, Hans, Chen, Jiawen, Feringa, Ben L
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container_end_page 11828
container_issue 36
container_start_page 11821
container_title Langmuir
container_volume 35
creator Tosi, Filippo
Stuart, Marc C. A
Smit, Hans
Chen, Jiawen
Feringa, Ben L
description The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple sonication induced the rearrangement of different kinetically stable aggregates into thermodynamically stable self-assembled nanotubes, as observed by cryo-TEM.
doi_str_mv 10.1021/acs.langmuir.9b01989
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title Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-Derived Amphiphiles in Water
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