Carbon Monoxide Poisoning Resistance and Structural Stability of Single Atom Alloys

Platinum group metals (PGMs) serve as highly active catalysts in a variety of heterogeneous chemical processes. Unfortunately, their high activity is accompanied by a high affinity for CO and thus, PGMs are susceptible to poisoning. Alloying PGMs with metals exhibiting lower affinity to CO could be...

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Veröffentlicht in:	Topics in catalysis 2018, Vol.61 (5-6), p.428-438
Hauptverfasser:	Darby, Matthew T., Sykes, E. Charles H., Michaelides, Angelos, Stamatakis, Michail
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Affinity Agglomeration Alloy plating Atomic structure Carbon monoxide Carbon monoxide poisoning Catalysis Catalyst poisoning Catalyst stability Catalysts Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Computer simulation Constitution Copper Density functional theory Dilution Dopants Ensemble effects Gold Highly dilute alloy Industrial Chemistry/Chemical Engineering INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Iridium MATERIALS SCIENCE Mathematical analysis Metals Monte Carlo simulation Nickel Original Paper Pharmacy Physical Chemistry Platinum Platinum group metals Poisoning Poisons Silver Structural stability Surface chemistry Surface layers Surface stability
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