C–H Hydroxylation in Paralytic Shellfish Toxin Biosynthesis

The remarkable degree of synthetic selectivity found in Nature is exemplified by the biosynthesis of paralytic shellfish toxins such as saxitoxin. The polycyclic core shared by saxitoxin and its relatives is assembled and subsequently elaborated through the installation of hydroxyl groups with exqui...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-09, Vol.140 (37), p.11863-11869
Hauptverfasser:	Lukowski, April L, Ellinwood, Duncan C, Hinze, Meagan E, DeLuca, Ryan J, Du Bois, J, Hall, Sherwood, Narayan, Alison R. H
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals biochemical pathways biosynthesis catalysts Hydroxylation Marine Toxins - biosynthesis Marine Toxins - chemistry Models, Molecular moieties Molecular Structure oxidation oxygenases paralytic shellfish toxins Shellfish stereoselectivity
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