Umpolung α‑Silylation of Cyclopropyl Acetates via Low-Temperature Catalytic C–C Activation

We report a redox-neutral, catalytic C–C activation of cyclopropyl acetates to produce silicon-containing five-membered heterocycles in a highly regio- and chemoselective fashion. The umpolung α-selective silylation leading to dioxasilolanes is opposed to contemporary β-selective C–C functionalizati...

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Veröffentlicht in:	ACS catalysis 2019-01, Vol.9 (1), p.402-408
Hauptverfasser:	Avullala, Thirupataiah, Asgari, Parham, Hua, Yuanda, Bokka, Apparao, Ridlen, Shawn G, Yum, Kyungsuk, Dias, H. V. Rasika, Jeon, Junha
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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