Post-tilleyite, a dense calcium silicate-carbonate phase
Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behav...
Gespeichert in:
| Veröffentlicht in: | Scientific reports 2019-05, Vol.9 (1), p.7898-7898, Article 7898 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7898 |
|---|---|
| container_issue | 1 |
| container_start_page | 7898 |
| container_title | Scientific reports |
| container_volume | 9 |
| creator | Santamaria-Perez, David Ruiz-Fuertes, Javier Peña-Alvarez, Miriam Chulia-Jordan, Raquel Marqueño, Tomas Zimmer, Dominik Gutiérrez-Cano, Vanessa MacLeod, Simon Gregoryanz, Eugene Popescu, Catalin Rodríguez-Hernández, Plácida Muñoz, Alfonso |
| description | Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca
5
(Si
2
O
7
)(CO
3
)
2
tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and
ab-initio
simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies. |
| doi_str_mv | 10.1038/s41598-019-44326-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6536543</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2232107309</sourcerecordid><originalsourceid>FETCH-LOGICAL-c474t-526ed07fef87cb002e4d73aa3414680a159de50ca5a128c5bef783d3da6202db3</originalsourceid><addsrcrecordid>eNp9kctKxDAUhoMoKjov4EIKblwYPbm23QgyeANBF7oOaXo6RjrtmLSCb2_G8b4wmxw4X77k5Cdkj8ExA1GcRMlUWVBgJZVScE3LNbLNQSrKBefrP-otMonxCdJSvJSs3CRbgjEhdF5uk-KujwMdfNviqx_wKLNZjV3EzNnW-XGeRd96Zwekzoaq71KVLR5txF2y0dg24uRj3yEPF-f30yt6c3t5PT27oU7mcqCKa6whb7ApclcBcJR1LqwVkkldgE1D1KjAWWUZL5yqsMkLUYvaag68rsQOOV15F2M1x9phNwTbmkXwcxteTW-9-d3p_KOZ9S9GK6GVFElw-CEI_fOIcTBzHx22re2wH6Ph6Y8Y5ALKhB78QZ_6MXRpvCUFmmuApZCvKBf6GAM2X49hYJbZmFU2JmVj3rMxS_X-zzG-jnwmkQCxAmJqdTMM33f_o30DS5WZXg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2230626003</pqid></control><display><type>article</type><title>Post-tilleyite, a dense calcium silicate-carbonate phase</title><source>Nature Free</source><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>Alma/SFX Local Collection</source><source>Free Full-Text Journals in Chemistry</source><source>Springer Nature OA Free Journals</source><creator>Santamaria-Perez, David ; Ruiz-Fuertes, Javier ; Peña-Alvarez, Miriam ; Chulia-Jordan, Raquel ; Marqueño, Tomas ; Zimmer, Dominik ; Gutiérrez-Cano, Vanessa ; MacLeod, Simon ; Gregoryanz, Eugene ; Popescu, Catalin ; Rodríguez-Hernández, Plácida ; Muñoz, Alfonso</creator><creatorcontrib>Santamaria-Perez, David ; Ruiz-Fuertes, Javier ; Peña-Alvarez, Miriam ; Chulia-Jordan, Raquel ; Marqueño, Tomas ; Zimmer, Dominik ; Gutiérrez-Cano, Vanessa ; MacLeod, Simon ; Gregoryanz, Eugene ; Popescu, Catalin ; Rodríguez-Hernández, Plácida ; Muñoz, Alfonso</creatorcontrib><description>Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca
5
(Si
2
O
7
)(CO
3
)
2
tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and
ab-initio
simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-019-44326-9</identifier><identifier>PMID: 31133679</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>119/118 ; 140/133 ; 639/301/119 ; 704/2151/330 ; Aluminum oxide ; Calcium carbonate ; Carbon ; Cations ; Compression ; High temperature ; Humanities and Social Sciences ; Minerals ; multidisciplinary ; Powder ; Raman spectroscopy ; Science ; Science (multidisciplinary) ; Silica ; Silicates ; Spectrum analysis ; Structural behavior</subject><ispartof>Scientific reports, 2019-05, Vol.9 (1), p.7898-7898, Article 7898</ispartof><rights>The Author(s) 2019</rights><rights>The Author(s) 2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c474t-526ed07fef87cb002e4d73aa3414680a159de50ca5a128c5bef783d3da6202db3</citedby><cites>FETCH-LOGICAL-c474t-526ed07fef87cb002e4d73aa3414680a159de50ca5a128c5bef783d3da6202db3</cites><orcidid>0000-0001-9080-8756 ; 0000-0001-7056-7158 ; 0000-0002-1119-5056 ; 0000-0001-6613-4739</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6536543/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6536543/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,41096,42165,51551,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31133679$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Santamaria-Perez, David</creatorcontrib><creatorcontrib>Ruiz-Fuertes, Javier</creatorcontrib><creatorcontrib>Peña-Alvarez, Miriam</creatorcontrib><creatorcontrib>Chulia-Jordan, Raquel</creatorcontrib><creatorcontrib>Marqueño, Tomas</creatorcontrib><creatorcontrib>Zimmer, Dominik</creatorcontrib><creatorcontrib>Gutiérrez-Cano, Vanessa</creatorcontrib><creatorcontrib>MacLeod, Simon</creatorcontrib><creatorcontrib>Gregoryanz, Eugene</creatorcontrib><creatorcontrib>Popescu, Catalin</creatorcontrib><creatorcontrib>Rodríguez-Hernández, Plácida</creatorcontrib><creatorcontrib>Muñoz, Alfonso</creatorcontrib><title>Post-tilleyite, a dense calcium silicate-carbonate phase</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca
5
(Si
2
O
7
)(CO
3
)
2
tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and
ab-initio
simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.</description><subject>119/118</subject><subject>140/133</subject><subject>639/301/119</subject><subject>704/2151/330</subject><subject>Aluminum oxide</subject><subject>Calcium carbonate</subject><subject>Carbon</subject><subject>Cations</subject><subject>Compression</subject><subject>High temperature</subject><subject>Humanities and Social Sciences</subject><subject>Minerals</subject><subject>multidisciplinary</subject><subject>Powder</subject><subject>Raman spectroscopy</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Silica</subject><subject>Silicates</subject><subject>Spectrum analysis</subject><subject>Structural behavior</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp9kctKxDAUhoMoKjov4EIKblwYPbm23QgyeANBF7oOaXo6RjrtmLSCb2_G8b4wmxw4X77k5Cdkj8ExA1GcRMlUWVBgJZVScE3LNbLNQSrKBefrP-otMonxCdJSvJSs3CRbgjEhdF5uk-KujwMdfNviqx_wKLNZjV3EzNnW-XGeRd96Zwekzoaq71KVLR5txF2y0dg24uRj3yEPF-f30yt6c3t5PT27oU7mcqCKa6whb7ApclcBcJR1LqwVkkldgE1D1KjAWWUZL5yqsMkLUYvaag68rsQOOV15F2M1x9phNwTbmkXwcxteTW-9-d3p_KOZ9S9GK6GVFElw-CEI_fOIcTBzHx22re2wH6Ph6Y8Y5ALKhB78QZ_6MXRpvCUFmmuApZCvKBf6GAM2X49hYJbZmFU2JmVj3rMxS_X-zzG-jnwmkQCxAmJqdTMM33f_o30DS5WZXg</recordid><startdate>20190527</startdate><enddate>20190527</enddate><creator>Santamaria-Perez, David</creator><creator>Ruiz-Fuertes, Javier</creator><creator>Peña-Alvarez, Miriam</creator><creator>Chulia-Jordan, Raquel</creator><creator>Marqueño, Tomas</creator><creator>Zimmer, Dominik</creator><creator>Gutiérrez-Cano, Vanessa</creator><creator>MacLeod, Simon</creator><creator>Gregoryanz, Eugene</creator><creator>Popescu, Catalin</creator><creator>Rodríguez-Hernández, Plácida</creator><creator>Muñoz, Alfonso</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9080-8756</orcidid><orcidid>https://orcid.org/0000-0001-7056-7158</orcidid><orcidid>https://orcid.org/0000-0002-1119-5056</orcidid><orcidid>https://orcid.org/0000-0001-6613-4739</orcidid></search><sort><creationdate>20190527</creationdate><title>Post-tilleyite, a dense calcium silicate-carbonate phase</title><author>Santamaria-Perez, David ; Ruiz-Fuertes, Javier ; Peña-Alvarez, Miriam ; Chulia-Jordan, Raquel ; Marqueño, Tomas ; Zimmer, Dominik ; Gutiérrez-Cano, Vanessa ; MacLeod, Simon ; Gregoryanz, Eugene ; Popescu, Catalin ; Rodríguez-Hernández, Plácida ; Muñoz, Alfonso</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c474t-526ed07fef87cb002e4d73aa3414680a159de50ca5a128c5bef783d3da6202db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>119/118</topic><topic>140/133</topic><topic>639/301/119</topic><topic>704/2151/330</topic><topic>Aluminum oxide</topic><topic>Calcium carbonate</topic><topic>Carbon</topic><topic>Cations</topic><topic>Compression</topic><topic>High temperature</topic><topic>Humanities and Social Sciences</topic><topic>Minerals</topic><topic>multidisciplinary</topic><topic>Powder</topic><topic>Raman spectroscopy</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Silica</topic><topic>Silicates</topic><topic>Spectrum analysis</topic><topic>Structural behavior</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Santamaria-Perez, David</creatorcontrib><creatorcontrib>Ruiz-Fuertes, Javier</creatorcontrib><creatorcontrib>Peña-Alvarez, Miriam</creatorcontrib><creatorcontrib>Chulia-Jordan, Raquel</creatorcontrib><creatorcontrib>Marqueño, Tomas</creatorcontrib><creatorcontrib>Zimmer, Dominik</creatorcontrib><creatorcontrib>Gutiérrez-Cano, Vanessa</creatorcontrib><creatorcontrib>MacLeod, Simon</creatorcontrib><creatorcontrib>Gregoryanz, Eugene</creatorcontrib><creatorcontrib>Popescu, Catalin</creatorcontrib><creatorcontrib>Rodríguez-Hernández, Plácida</creatorcontrib><creatorcontrib>Muñoz, Alfonso</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Santamaria-Perez, David</au><au>Ruiz-Fuertes, Javier</au><au>Peña-Alvarez, Miriam</au><au>Chulia-Jordan, Raquel</au><au>Marqueño, Tomas</au><au>Zimmer, Dominik</au><au>Gutiérrez-Cano, Vanessa</au><au>MacLeod, Simon</au><au>Gregoryanz, Eugene</au><au>Popescu, Catalin</au><au>Rodríguez-Hernández, Plácida</au><au>Muñoz, Alfonso</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Post-tilleyite, a dense calcium silicate-carbonate phase</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2019-05-27</date><risdate>2019</risdate><volume>9</volume><issue>1</issue><spage>7898</spage><epage>7898</epage><pages>7898-7898</pages><artnum>7898</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca
5
(Si
2
O
7
)(CO
3
)
2
tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and
ab-initio
simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>31133679</pmid><doi>10.1038/s41598-019-44326-9</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-9080-8756</orcidid><orcidid>https://orcid.org/0000-0001-7056-7158</orcidid><orcidid>https://orcid.org/0000-0002-1119-5056</orcidid><orcidid>https://orcid.org/0000-0001-6613-4739</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2045-2322 |
| ispartof | Scientific reports, 2019-05, Vol.9 (1), p.7898-7898, Article 7898 |
| issn | 2045-2322 2045-2322 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6536543 |
| source | Nature Free; DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry; Springer Nature OA Free Journals |
| subjects | 119/118 140/133 639/301/119 704/2151/330 Aluminum oxide Calcium carbonate Carbon Cations Compression High temperature Humanities and Social Sciences Minerals multidisciplinary Powder Raman spectroscopy Science Science (multidisciplinary) Silica Silicates Spectrum analysis Structural behavior |
| title | Post-tilleyite, a dense calcium silicate-carbonate phase |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-03T00%3A10%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Post-tilleyite,%20a%20dense%20calcium%20silicate-carbonate%20phase&rft.jtitle=Scientific%20reports&rft.au=Santamaria-Perez,%20David&rft.date=2019-05-27&rft.volume=9&rft.issue=1&rft.spage=7898&rft.epage=7898&rft.pages=7898-7898&rft.artnum=7898&rft.issn=2045-2322&rft.eissn=2045-2322&rft_id=info:doi/10.1038/s41598-019-44326-9&rft_dat=%3Cproquest_pubme%3E2232107309%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2230626003&rft_id=info:pmid/31133679&rfr_iscdi=true |