Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles

Catalytic carbonyl-olefin metathesis reactions have recently been developed as a powerful tool for carbon–carbon bond formation. However, currently available synthetic protocols rely exclusively on aryl ketone substrates while the corresponding aliphatic analogs remain elusive. We herein report the...

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Veröffentlicht in:	Journal of the American Chemical Society 2019-01, Vol.141 (4), p.1690-1700
Hauptverfasser:	Albright, Haley, Riehl, Paul S, McAtee, Christopher C, Reid, Jolene P, Ludwig, Jacob R, Karp, Lindsey A, Zimmerman, Paul M, Sigman, Matthew S, Schindler, Corinna S
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Catalysis catalysts catalytic activity chemical bonding Dimerization iron Iron - chemistry ketones Ketones - chemistry Lewis acids Lewis Acids - chemistry Models, Molecular Molecular Conformation
Online-Zugang:	Volltext
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