Carboxylic acid stimulated silver shell isomerism in a triple core–shell Ag84 nanocluster

Isomerization is highly important in all aspects of science, yet it is rarely observed in nanoscience. Here, we synthesized a unique triple core–shell Ag84 nanocluster displaying isomerism, which is controlled by different carboxylic acids and a one-way transformation (SD/Ag84a → SD/Ag84b). The inne...

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Veröffentlicht in:	Chemical science (Cambridge) 2019, Vol.10 (18), p.4862-4867
Hauptverfasser:	Wang, Zhi, Hao-Tian, Sun, Kurmoo, Mohamedally, Qing-Yun, Liu, Gui-Lin, Zhuang, Quan-Qin, Zhao, Xing-Po, Wang, Chen-Ho, Tung, Sun, Di
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic acids Chemistry Crystal structure Crystallography Crystals Data acquisition Isomerization Metal shells Nanoclusters NMR Nuclear magnetic resonance Silver Steric hindrance
Online-Zugang:	Volltext
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