Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer

The use of pyridinium‐activated primary amines as photoactive functional groups for deaminative generation of alkyl radicals under catalyst‐free conditions is described. By taking advantage of the visible light absorptivity of electron donor–acceptor complexes between Katritzky pyridinium salts and...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-04, Vol.58 (17), p.5697-5701
Hauptverfasser:	Wu, Jingjing, Grant, Phillip S., Li, Xiabing, Noble, Adam, Aggarwal, Varinder K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorptivity Alkylation Allyl compounds Amines Catalysis Catalysts Chemical reactions Communication Communications Coordination compounds deamination electron donor–acceptor complexes Electron transfer Electrons Free radicals Functional groups Giese reactions photochemistry Pyridinium radical reactions Salts
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