Photoredox Catalysis Enables Access to N‑Functionalized 2,1-Borazaronaphthalenes

The synthesis and utilization of a class of 2,1-borazaronaphthyltrifluoroborate reagents that provide a general solution to the challenge of N-functionalization of the 2,1-borazaronaphthalene core is described. By adorning the nitrogen of this core with a trifluoroboratomethyl unit, a suite of odd-e...

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Veröffentlicht in:	Organic letters 2019-04, Vol.21 (8), p.2880-2884
Hauptverfasser:	Wang, Xie, Davies, Geraint H. M, Koschitzky, Adriel, Wisniewski, Steven R, Kelly, Christopher B, Molander, Gary A
Format:	Artikel
Sprache:	eng
Schlagworte:	Borates - chemistry Catalysis Coordination Complexes - chemistry Iridium - chemistry Naphthalenes - chemical synthesis Nickel - chemistry Oxidation-Reduction Photochemical Processes Ruthenium - chemistry
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