PLA with Intumescent System Containing Lignin and Ammonium Polyphosphate for Flame Retardant Textile
Using bio-based polymers to replace of polymers from petrochemicals in the manufacture of textile fibers is a possible way to improve sustainable development for the textile industry. Polylactic acid (PLA) is one of the available bio-based polymers. One way to improve the fire behavior of this bio-b...
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| Veröffentlicht in: | Polymers 2016-09, Vol.8 (9), p.331-331 |
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| creator | Cayla, Aurélie Rault, François Giraud, Stéphane Salaün, Fabien Fierro, Vanessa Celzard, Alain |
| description | Using bio-based polymers to replace of polymers from petrochemicals in the manufacture of textile fibers is a possible way to improve sustainable development for the textile industry. Polylactic acid (PLA) is one of the available bio-based polymers. One way to improve the fire behavior of this bio-based polymer is to add an intumescent formulation mainly composed of acid and carbon sources. In order to optimize the amount of bio-based product in the final material composition, lignin from wood waste was selected as the carbon source. Different formulations of and/or ammonium polyphosphate (AP) were prepared by melt extrusion and then hot-pressed into sheets. The thermal properties (thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC)) and fire properties (UL-94) were measured. The spinnability of the various composites was evaluated. The mechanical properties and physical aspect (microscopy) of PLA multifilaments with lignin (LK) were checked. A PLA multifilament with up to 10 wt % of intumescent formulation was processed, and the fire behavior of PLA fabrics with lignin/AP formulation was studied by cone calorimeter. |
| doi_str_mv | 10.3390/polym8090331 |
| format | Article |
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Polylactic acid (PLA) is one of the available bio-based polymers. One way to improve the fire behavior of this bio-based polymer is to add an intumescent formulation mainly composed of acid and carbon sources. In order to optimize the amount of bio-based product in the final material composition, lignin from wood waste was selected as the carbon source. Different formulations of and/or ammonium polyphosphate (AP) were prepared by melt extrusion and then hot-pressed into sheets. The thermal properties (thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC)) and fire properties (UL-94) were measured. The spinnability of the various composites was evaluated. The mechanical properties and physical aspect (microscopy) of PLA multifilaments with lignin (LK) were checked. A PLA multifilament with up to 10 wt % of intumescent formulation was processed, and the fire behavior of PLA fabrics with lignin/AP formulation was studied by cone calorimeter.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym8090331</identifier><identifier>PMID: 30974606</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Biopolymers ; Carbon ; Differential scanning calorimetry ; Formulations ; Intumescent ; Polymers ; Polyphosphates ; Textiles</subject><ispartof>Polymers, 2016-09, Vol.8 (9), p.331-331</ispartof><rights>Copyright MDPI AG 2016</rights><rights>2016 by the authors. 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c445t-6a523c03121da6330ba5be6e2c40ddb789128804b61cbf0fe13ea1b2269f90f23</citedby><cites>FETCH-LOGICAL-c445t-6a523c03121da6330ba5be6e2c40ddb789128804b61cbf0fe13ea1b2269f90f23</cites><orcidid>0000-0003-0073-9545 ; 0000-0002-1405-4830 ; 0000-0001-5031-3396 ; 0000-0002-0712-6250</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431874/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431874/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,725,778,782,883,27907,27908,53774,53776</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30974606$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cayla, Aurélie</creatorcontrib><creatorcontrib>Rault, François</creatorcontrib><creatorcontrib>Giraud, Stéphane</creatorcontrib><creatorcontrib>Salaün, Fabien</creatorcontrib><creatorcontrib>Fierro, Vanessa</creatorcontrib><creatorcontrib>Celzard, Alain</creatorcontrib><title>PLA with Intumescent System Containing Lignin and Ammonium Polyphosphate for Flame Retardant Textile</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>Using bio-based polymers to replace of polymers from petrochemicals in the manufacture of textile fibers is a possible way to improve sustainable development for the textile industry. Polylactic acid (PLA) is one of the available bio-based polymers. One way to improve the fire behavior of this bio-based polymer is to add an intumescent formulation mainly composed of acid and carbon sources. In order to optimize the amount of bio-based product in the final material composition, lignin from wood waste was selected as the carbon source. Different formulations of and/or ammonium polyphosphate (AP) were prepared by melt extrusion and then hot-pressed into sheets. The thermal properties (thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC)) and fire properties (UL-94) were measured. The spinnability of the various composites was evaluated. The mechanical properties and physical aspect (microscopy) of PLA multifilaments with lignin (LK) were checked. A PLA multifilament with up to 10 wt % of intumescent formulation was processed, and the fire behavior of PLA fabrics with lignin/AP formulation was studied by cone calorimeter.</description><subject>Biopolymers</subject><subject>Carbon</subject><subject>Differential scanning calorimetry</subject><subject>Formulations</subject><subject>Intumescent</subject><subject>Polymers</subject><subject>Polyphosphates</subject><subject>Textiles</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFkc1r3DAQxUVJaUKaW89BkEsO3Xb0Ydm6BJalaQMLDW16FrIt7ypYkiPJafe_r0LSsMmluoxgfryZNw-hDwQ-MSbh8xTGnWtAAmPkDTqiULMFZwIO9v6H6CSlWyiPV0KQ-h06ZCBrLkAcof56vcS_bd7iK59nZ1JnfMY_dykbh1fBZ2299Ru8tptSsfY9XjoXvJ0dvi7Dp21I01Zng4cQ8eWoncE_TNax10XnxvzJdjTv0dtBj8mcPNVj9Ovyy83q22L9_evVarledJxXeSF0RVkHjFDSa8EYtLpqjTC049D3bd1IQpsGeCtI1w4wGMKMJi2lQg4SBsqO0cWj7jS3zvQPVqIe1RSt03GngrbqZcfbrdqEeyU4I03Ni8D5k0AMd7NJWTlbLjKO2pswJ0UpSAGUNc1_UdLwqpaEESjo2Sv0NszRl0sUihRTUAlZqI-PVBdDStEMz3sTUA9hq_2wC3667_UZ_hct-wsllqYU</recordid><startdate>20160905</startdate><enddate>20160905</enddate><creator>Cayla, Aurélie</creator><creator>Rault, François</creator><creator>Giraud, Stéphane</creator><creator>Salaün, Fabien</creator><creator>Fierro, Vanessa</creator><creator>Celzard, Alain</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-0073-9545</orcidid><orcidid>https://orcid.org/0000-0002-1405-4830</orcidid><orcidid>https://orcid.org/0000-0001-5031-3396</orcidid><orcidid>https://orcid.org/0000-0002-0712-6250</orcidid></search><sort><creationdate>20160905</creationdate><title>PLA with Intumescent System Containing Lignin and Ammonium Polyphosphate for Flame Retardant Textile</title><author>Cayla, Aurélie ; 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| subjects | Biopolymers Carbon Differential scanning calorimetry Formulations Intumescent Polymers Polyphosphates Textiles |
| title | PLA with Intumescent System Containing Lignin and Ammonium Polyphosphate for Flame Retardant Textile |
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