A Diverted Aerobic Heck Reaction Enables Selective 1,3-Diene and 1,3,5-Triene Synthesis through C–C Bond Scission

Substituted 1,3-dienes are valuable synthetic intermediates used in myriad catalytic transformations, yet modern catalytic methods for their preparation in a highly modular fashion using simple precursors are relatively few. We report here an aerobic boron Heck reaction with cyclobutene that forms e...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-10, Vol.140 (42), p.13634-13639
Hauptverfasser:	McAlpine, Neil J, Wang, Long, Carrow, Brad P
Format:	Artikel
Sprache:	eng
Schlagworte:	acids Alkenes - chemical synthesis Alkenes - chemistry boron Boronic Acids - chemical synthesis Boronic Acids - chemistry chemical bonding Chemistry Techniques, Synthetic cleavage (chemistry) Cyclobutanes - chemical synthesis Cyclobutanes - chemistry Oxygen - chemistry Stereoisomerism
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