Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride)
A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and ¹H NMR. The effects of replacement of petroleum-bas...
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| Veröffentlicht in: | Polymers 2017-11, Vol.9 (12), p.640 |
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| creator | Chen, Jie Li, Ke Wang, Yigang Huang, Jinrui Nie, Xiaoan Jiang, Jianchun |
| description | A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and ¹H NMR. The effects of replacement of petroleum-based commercial plasticizer dioctyl phthalate (DOP) with EGERAE in poly(vinyl chloride) (PVC) films were researched. Thermal stability, dynamic mechanical property and mechanical properties of PVC films were investigated with thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests. The results indicated that this castor oil-based plasticizer was able to improve the thermal stability of PVC blends when partially of completely substituting for DOP. Furthermore, EGERAE endowed PVC resin with enhanced flexibility. In addition, the exudation, volatility and extraction resistance characteristics of plasticizers were researched. The degradation mechanism and possible interaction between EGERAE and PVC molecules in the plasticized system were also investigated. |
| doi_str_mv | 10.3390/polym9120640 |
| format | Article |
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Its molecular structure was characterized by FT-IR and ¹H NMR. The effects of replacement of petroleum-based commercial plasticizer dioctyl phthalate (DOP) with EGERAE in poly(vinyl chloride) (PVC) films were researched. Thermal stability, dynamic mechanical property and mechanical properties of PVC films were investigated with thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests. The results indicated that this castor oil-based plasticizer was able to improve the thermal stability of PVC blends when partially of completely substituting for DOP. Furthermore, EGERAE endowed PVC resin with enhanced flexibility. In addition, the exudation, volatility and extraction resistance characteristics of plasticizers were researched. The degradation mechanism and possible interaction between EGERAE and PVC molecules in the plasticized system were also investigated.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym9120640</identifier><identifier>PMID: 30965956</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Castor oil ; Chemical industry ; Dioctyl phthalate ; Dynamic mechanical analysis ; Dynamic stability ; Exudation ; Glycidyl esters ; Mechanical properties ; Molecular structure ; NMR ; Nuclear magnetic resonance ; Plasticizers ; Polymer blends ; Polyvinyl chloride ; Tensile tests ; Thermal stability ; Thermogravimetric analysis ; Volatility</subject><ispartof>Polymers, 2017-11, Vol.9 (12), p.640</ispartof><rights>Copyright MDPI AG 2017</rights><rights>2017 by the authors. 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c478t-6851626b612db802afe52e81f364127e9aafd6494bdd2a71296d7f68a1736b4b3</citedby><cites>FETCH-LOGICAL-c478t-6851626b612db802afe52e81f364127e9aafd6494bdd2a71296d7f68a1736b4b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418936/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6418936/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30965956$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Jie</creatorcontrib><creatorcontrib>Li, Ke</creatorcontrib><creatorcontrib>Wang, Yigang</creatorcontrib><creatorcontrib>Huang, Jinrui</creatorcontrib><creatorcontrib>Nie, Xiaoan</creatorcontrib><creatorcontrib>Jiang, Jianchun</creatorcontrib><title>Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride)</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and ¹H NMR. The effects of replacement of petroleum-based commercial plasticizer dioctyl phthalate (DOP) with EGERAE in poly(vinyl chloride) (PVC) films were researched. Thermal stability, dynamic mechanical property and mechanical properties of PVC films were investigated with thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests. The results indicated that this castor oil-based plasticizer was able to improve the thermal stability of PVC blends when partially of completely substituting for DOP. Furthermore, EGERAE endowed PVC resin with enhanced flexibility. In addition, the exudation, volatility and extraction resistance characteristics of plasticizers were researched. The degradation mechanism and possible interaction between EGERAE and PVC molecules in the plasticized system were also investigated.</description><subject>Castor oil</subject><subject>Chemical industry</subject><subject>Dioctyl phthalate</subject><subject>Dynamic mechanical analysis</subject><subject>Dynamic stability</subject><subject>Exudation</subject><subject>Glycidyl esters</subject><subject>Mechanical properties</subject><subject>Molecular structure</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Plasticizers</subject><subject>Polymer blends</subject><subject>Polyvinyl chloride</subject><subject>Tensile tests</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Volatility</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUU1v1DAQtRCIVqU3zigSl1ZiwR-JE1-QqqoUpAoqPs6WY09YV44d7OyK8Bf6pzvVlmrBl_HzvPc040fIS0bfCqHouymFZVSMU1nTJ-SQ01asaiHp0737ATku5YbiqRspWfucHAiqZKMaeUhuvy1xXkPxpTLRVdc5TZBnD6VKQ2Wqz2kLobqIW59THCHOBtGUfnvn_4CrLsNivVvwrcyQ7yVfvfUxBfC2OrMwY9m1roMpiFCVqyEhxsFPtj6i1q5Dyt7B6QvybDChwPFDPSI_Plx8P_-4uvpy-en87Gpl67abV7JrmOSyl4y7vqPcDNBw6NggZM14C8qYwcla1b1z3LSMK-naQXaGtUL2dS-OyPud77TpR3AW18om6Cn70eRFJ-P1v53o1_pn2mr075SQaHDyYJDTrw2UWY--WAjBREibojn-PZNKNBSpr_-j3qRNjrieZkphbpR2DFlvdiybUykZhsdhGNX3Qev9oJH-an-BR_LfWMUd-Xqmzw</recordid><startdate>20171129</startdate><enddate>20171129</enddate><creator>Chen, Jie</creator><creator>Li, Ke</creator><creator>Wang, Yigang</creator><creator>Huang, Jinrui</creator><creator>Nie, Xiaoan</creator><creator>Jiang, Jianchun</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20171129</creationdate><title>Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride)</title><author>Chen, Jie ; Li, Ke ; Wang, Yigang ; Huang, Jinrui ; Nie, Xiaoan ; Jiang, Jianchun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c478t-6851626b612db802afe52e81f364127e9aafd6494bdd2a71296d7f68a1736b4b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Castor oil</topic><topic>Chemical industry</topic><topic>Dioctyl phthalate</topic><topic>Dynamic mechanical analysis</topic><topic>Dynamic stability</topic><topic>Exudation</topic><topic>Glycidyl esters</topic><topic>Mechanical properties</topic><topic>Molecular structure</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Plasticizers</topic><topic>Polymer blends</topic><topic>Polyvinyl chloride</topic><topic>Tensile tests</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><topic>Volatility</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Jie</creatorcontrib><creatorcontrib>Li, Ke</creatorcontrib><creatorcontrib>Wang, Yigang</creatorcontrib><creatorcontrib>Huang, Jinrui</creatorcontrib><creatorcontrib>Nie, Xiaoan</creatorcontrib><creatorcontrib>Jiang, Jianchun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Jie</au><au>Li, Ke</au><au>Wang, Yigang</au><au>Huang, Jinrui</au><au>Nie, Xiaoan</au><au>Jiang, Jianchun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride)</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2017-11-29</date><risdate>2017</risdate><volume>9</volume><issue>12</issue><spage>640</spage><pages>640-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>A novel renewable plasticizer based on castor oil, epoxidized glycidyl ester of ricinoleic acetic ester (EGERAE), was synthesized and applied into Poly(vinyl chloride) (PVC) for the first time. Its molecular structure was characterized by FT-IR and ¹H NMR. The effects of replacement of petroleum-based commercial plasticizer dioctyl phthalate (DOP) with EGERAE in poly(vinyl chloride) (PVC) films were researched. Thermal stability, dynamic mechanical property and mechanical properties of PVC films were investigated with thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests. The results indicated that this castor oil-based plasticizer was able to improve the thermal stability of PVC blends when partially of completely substituting for DOP. Furthermore, EGERAE endowed PVC resin with enhanced flexibility. In addition, the exudation, volatility and extraction resistance characteristics of plasticizers were researched. The degradation mechanism and possible interaction between EGERAE and PVC molecules in the plasticized system were also investigated.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>30965956</pmid><doi>10.3390/polym9120640</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Castor oil Chemical industry Dioctyl phthalate Dynamic mechanical analysis Dynamic stability Exudation Glycidyl esters Mechanical properties Molecular structure NMR Nuclear magnetic resonance Plasticizers Polymer blends Polyvinyl chloride Tensile tests Thermal stability Thermogravimetric analysis Volatility |
| title | Synthesis and Properties of a Novel Environmental Epoxidized Glycidyl Ester of Ricinoleic Acetic Ester Plasticizer for Poly(vinyl chloride) |
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