Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks
Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved be...
Gespeichert in:
| Veröffentlicht in: | Advanced science 2019-01, Vol.6 (2), p.1801304-n/a |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 2 |
| container_start_page | 1801304 |
| container_title | Advanced science |
| container_volume | 6 |
| creator | Wu, Xiao‐Hui Luo, Peng Wei, Zhong Li, Yuan‐Yuan Huang, Ren‐Wu Dong, Xi‐Yan Li, Kai Zang, Shuang‐Quan Tang, Ben Zhong |
| description | Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved because of the rigid conformation of AIEgens in the crystalline state. Here, a dual‐node 3D silver chalcogenolate cluster MOF (1) is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations. The conformations of AIE ligands in 1 are switchable by the absorption/desorption of guest molecules. As a result, 1 exhibited not only intense but also guest molecule switched luminescent properties. More importantly, the switching rate is tunable by using different guest molecules. 1 provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in MOFs.
A dual‐node 3D silver chalcogenolate cluster metal–organic framework is designed and synthesized, which provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in metal–organic frameworks. |
| doi_str_mv | 10.1002/advs.201801304 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6343058</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2179445167</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5284-4320ba2ec3acdd800922e92492e97fc4b2d1c727c74bec9782a21d0de13a57853</originalsourceid><addsrcrecordid>eNqFkctuGyEYhVHVKonSbLOsRuqmG7vcxsCmkuVcGilVFrlsEYbfE1IMKcw4yi6PUKlvmCcpllMr7aYbQIePo_9wEDokeEwwpp-NW5UxxURiwjB_g_YoUXLEJOdvX5130UEpdxhj0jLBidxBuwxPFCOS7aFwOkDpn59-XmXfdZDBNdOuy9CZ3qdY9bPoBlvV46UvpUqNj82lDyvIzezWBJs6iCmYHppZGEpf5W_Qm_D89OsidyZ625xks4SHlL-X9-jdwoQCBy_7Pro-Ob6afR2dX5yezabnI9tSyUecUTw3FCwz1jmJsaIUFOWqrmJh-Zw6YgUVVvA5WCUkNZQ47IAw0wrZsn30ZeN7P8yX4CzEPpug77Nfmvyok_H675vob3WXVnrCOMOtrAafXgxy-rH-IF3TWwjBREhD0ZQIxXlLJqKiH_9B79KQY42nKVVYKMUxrdR4Q9mcSsmw2A5DsF53qddd6m2X9cGH1xG2-J_mKsA2wIMP8PgfOz09urmUkrPfb8GutA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2290799402</pqid></control><display><type>article</type><title>Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks</title><source>Wiley Online Library - AutoHoldings Journals</source><source>DOAJ Directory of Open Access Journals</source><source>Wiley Online Library Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Wu, Xiao‐Hui ; Luo, Peng ; Wei, Zhong ; Li, Yuan‐Yuan ; Huang, Ren‐Wu ; Dong, Xi‐Yan ; Li, Kai ; Zang, Shuang‐Quan ; Tang, Ben Zhong</creator><creatorcontrib>Wu, Xiao‐Hui ; Luo, Peng ; Wei, Zhong ; Li, Yuan‐Yuan ; Huang, Ren‐Wu ; Dong, Xi‐Yan ; Li, Kai ; Zang, Shuang‐Quan ; Tang, Ben Zhong</creatorcontrib><description>Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved because of the rigid conformation of AIEgens in the crystalline state. Here, a dual‐node 3D silver chalcogenolate cluster MOF (1) is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations. The conformations of AIE ligands in 1 are switchable by the absorption/desorption of guest molecules. As a result, 1 exhibited not only intense but also guest molecule switched luminescent properties. More importantly, the switching rate is tunable by using different guest molecules. 1 provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in MOFs.
A dual‐node 3D silver chalcogenolate cluster metal–organic framework is designed and synthesized, which provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in metal–organic frameworks.</description><identifier>ISSN: 2198-3844</identifier><identifier>EISSN: 2198-3844</identifier><identifier>DOI: 10.1002/advs.201801304</identifier><identifier>PMID: 30693183</identifier><language>eng</language><publisher>Germany: John Wiley & Sons, Inc</publisher><subject>aggregation‐induced emission ; cluster compounds ; Communication ; Communications ; crystal transformation ; host–guest chemistry ; Investigations ; Ligands ; Metal fatigue ; metal–organic frameworks ; Silver ; Spectrum analysis</subject><ispartof>Advanced science, 2019-01, Vol.6 (2), p.1801304-n/a</ispartof><rights>2018 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5284-4320ba2ec3acdd800922e92492e97fc4b2d1c727c74bec9782a21d0de13a57853</citedby><cites>FETCH-LOGICAL-c5284-4320ba2ec3acdd800922e92492e97fc4b2d1c727c74bec9782a21d0de13a57853</cites><orcidid>0000-0002-6728-0559</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6343058/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6343058/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,1417,11562,27924,27925,45574,45575,46052,46476,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30693183$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wu, Xiao‐Hui</creatorcontrib><creatorcontrib>Luo, Peng</creatorcontrib><creatorcontrib>Wei, Zhong</creatorcontrib><creatorcontrib>Li, Yuan‐Yuan</creatorcontrib><creatorcontrib>Huang, Ren‐Wu</creatorcontrib><creatorcontrib>Dong, Xi‐Yan</creatorcontrib><creatorcontrib>Li, Kai</creatorcontrib><creatorcontrib>Zang, Shuang‐Quan</creatorcontrib><creatorcontrib>Tang, Ben Zhong</creatorcontrib><title>Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks</title><title>Advanced science</title><addtitle>Adv Sci (Weinh)</addtitle><description>Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved because of the rigid conformation of AIEgens in the crystalline state. Here, a dual‐node 3D silver chalcogenolate cluster MOF (1) is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations. The conformations of AIE ligands in 1 are switchable by the absorption/desorption of guest molecules. As a result, 1 exhibited not only intense but also guest molecule switched luminescent properties. More importantly, the switching rate is tunable by using different guest molecules. 1 provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in MOFs.
A dual‐node 3D silver chalcogenolate cluster metal–organic framework is designed and synthesized, which provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in metal–organic frameworks.</description><subject>aggregation‐induced emission</subject><subject>cluster compounds</subject><subject>Communication</subject><subject>Communications</subject><subject>crystal transformation</subject><subject>host–guest chemistry</subject><subject>Investigations</subject><subject>Ligands</subject><subject>Metal fatigue</subject><subject>metal–organic frameworks</subject><subject>Silver</subject><subject>Spectrum analysis</subject><issn>2198-3844</issn><issn>2198-3844</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkctuGyEYhVHVKonSbLOsRuqmG7vcxsCmkuVcGilVFrlsEYbfE1IMKcw4yi6PUKlvmCcpllMr7aYbQIePo_9wEDokeEwwpp-NW5UxxURiwjB_g_YoUXLEJOdvX5130UEpdxhj0jLBidxBuwxPFCOS7aFwOkDpn59-XmXfdZDBNdOuy9CZ3qdY9bPoBlvV46UvpUqNj82lDyvIzezWBJs6iCmYHppZGEpf5W_Qm_D89OsidyZ625xks4SHlL-X9-jdwoQCBy_7Pro-Ob6afR2dX5yezabnI9tSyUecUTw3FCwz1jmJsaIUFOWqrmJh-Zw6YgUVVvA5WCUkNZQ47IAw0wrZsn30ZeN7P8yX4CzEPpug77Nfmvyok_H675vob3WXVnrCOMOtrAafXgxy-rH-IF3TWwjBREhD0ZQIxXlLJqKiH_9B79KQY42nKVVYKMUxrdR4Q9mcSsmw2A5DsF53qddd6m2X9cGH1xG2-J_mKsA2wIMP8PgfOz09urmUkrPfb8GutA</recordid><startdate>20190123</startdate><enddate>20190123</enddate><creator>Wu, Xiao‐Hui</creator><creator>Luo, Peng</creator><creator>Wei, Zhong</creator><creator>Li, Yuan‐Yuan</creator><creator>Huang, Ren‐Wu</creator><creator>Dong, Xi‐Yan</creator><creator>Li, Kai</creator><creator>Zang, Shuang‐Quan</creator><creator>Tang, Ben Zhong</creator><general>John Wiley & Sons, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>M2O</scope><scope>M2P</scope><scope>MBDVC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6728-0559</orcidid></search><sort><creationdate>20190123</creationdate><title>Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks</title><author>Wu, Xiao‐Hui ; Luo, Peng ; Wei, Zhong ; Li, Yuan‐Yuan ; Huang, Ren‐Wu ; Dong, Xi‐Yan ; Li, Kai ; Zang, Shuang‐Quan ; Tang, Ben Zhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5284-4320ba2ec3acdd800922e92492e97fc4b2d1c727c74bec9782a21d0de13a57853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>aggregation‐induced emission</topic><topic>cluster compounds</topic><topic>Communication</topic><topic>Communications</topic><topic>crystal transformation</topic><topic>host–guest chemistry</topic><topic>Investigations</topic><topic>Ligands</topic><topic>Metal fatigue</topic><topic>metal–organic frameworks</topic><topic>Silver</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Xiao‐Hui</creatorcontrib><creatorcontrib>Luo, Peng</creatorcontrib><creatorcontrib>Wei, Zhong</creatorcontrib><creatorcontrib>Li, Yuan‐Yuan</creatorcontrib><creatorcontrib>Huang, Ren‐Wu</creatorcontrib><creatorcontrib>Dong, Xi‐Yan</creatorcontrib><creatorcontrib>Li, Kai</creatorcontrib><creatorcontrib>Zang, Shuang‐Quan</creatorcontrib><creatorcontrib>Tang, Ben Zhong</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library Free Content</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Research Library (Corporate)</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Advanced science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Xiao‐Hui</au><au>Luo, Peng</au><au>Wei, Zhong</au><au>Li, Yuan‐Yuan</au><au>Huang, Ren‐Wu</au><au>Dong, Xi‐Yan</au><au>Li, Kai</au><au>Zang, Shuang‐Quan</au><au>Tang, Ben Zhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks</atitle><jtitle>Advanced science</jtitle><addtitle>Adv Sci (Weinh)</addtitle><date>2019-01-23</date><risdate>2019</risdate><volume>6</volume><issue>2</issue><spage>1801304</spage><epage>n/a</epage><pages>1801304-n/a</pages><issn>2198-3844</issn><eissn>2198-3844</eissn><abstract>Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved because of the rigid conformation of AIEgens in the crystalline state. Here, a dual‐node 3D silver chalcogenolate cluster MOF (1) is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations. The conformations of AIE ligands in 1 are switchable by the absorption/desorption of guest molecules. As a result, 1 exhibited not only intense but also guest molecule switched luminescent properties. More importantly, the switching rate is tunable by using different guest molecules. 1 provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in MOFs.
A dual‐node 3D silver chalcogenolate cluster metal–organic framework is designed and synthesized, which provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in metal–organic frameworks.</abstract><cop>Germany</cop><pub>John Wiley & Sons, Inc</pub><pmid>30693183</pmid><doi>10.1002/advs.201801304</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6728-0559</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2198-3844 |
| ispartof | Advanced science, 2019-01, Vol.6 (2), p.1801304-n/a |
| issn | 2198-3844 2198-3844 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6343058 |
| source | Wiley Online Library - AutoHoldings Journals; DOAJ Directory of Open Access Journals; Wiley Online Library Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | aggregation‐induced emission cluster compounds Communication Communications crystal transformation host–guest chemistry Investigations Ligands Metal fatigue metal–organic frameworks Silver Spectrum analysis |
| title | Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T09%3A16%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Guest%E2%80%90Triggered%20Aggregation%E2%80%90Induced%20Emission%20in%20Silver%20Chalcogenolate%20Cluster%20Metal%E2%80%93Organic%20Frameworks&rft.jtitle=Advanced%20science&rft.au=Wu,%20Xiao%E2%80%90Hui&rft.date=2019-01-23&rft.volume=6&rft.issue=2&rft.spage=1801304&rft.epage=n/a&rft.pages=1801304-n/a&rft.issn=2198-3844&rft.eissn=2198-3844&rft_id=info:doi/10.1002/advs.201801304&rft_dat=%3Cproquest_pubme%3E2179445167%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2290799402&rft_id=info:pmid/30693183&rfr_iscdi=true |