Direct observation of the intermediate in an ultrafast isomerization

Using a combination of two-dimensional infrared (2D IR) and variable temperature Fourier transform infrared (FTIR) spectroscopies the rapid structural isomerization of a five-coordinate ruthenium complex is investigated. In methylene chloride, three exchanging isomers were observed: (1) square pyram...

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Veröffentlicht in:	Chemical science (Cambridge) 2019-01, Vol.1 (1), p.113-117
Hauptverfasser:	Porter, Tyler M, Wang, Jiaxi, Li, Yingmin, Xiang, Bo, Salsman, Catherine, Miller, Joel S, Xiong, Wei, Kubiak, Clifford P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Coordination compounds Dichloromethane Exchanging Fourier transforms Isomerization Isomers Ruthenium compounds Time constant
Online-Zugang:	Volltext
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