Unlocking a Diazirine Long-Lived Nuclear Singlet State via Photochemistry: NMR Detection and Lifetime of an Unstabilized Diazo-Compound

Diazirines are important for photoaffinity labeling, and their photoisomerization is relatively well-known. This work shows how hyperpolarized NMR spectroscopy can be used to characterize an unstable diazo-compound formed via photoisomerization of a 15N2-labeled silyl-ether-substituted diazirine. Th...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-12, Vol.140 (48), p.16855-16864
Hauptverfasser:	Procacci, Barbara, Roy, Soumya S, Norcott, Philip, Turner, Norman, Duckett, Simon B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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