Visible‐Light‐Mediated Photoredox‐Catalyzed N‐Arylation of NH‐Sulfoximines with Electron‐Rich Arenes

The direct C−H/N−H dehydrogenative cross‐coupling of NH‐sulfoximines with electron‐rich arenes was realized by oxidative visible‐light photoredox catalysis, applying 9‐mesityl‐10‐methylacridinium perchlorate as an organic photocatalyst. Sulfoximines display diverse desirable properties for medicinal...

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Veröffentlicht in:	Advanced synthesis & catalysis 2018-09, Vol.360 (17), p.3277-3285
Hauptverfasser:	Wimmer, Alexander, König, Burkhard
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Alkylation Aromatic compounds Coupling cross-coupling Dehydrogenation Electrons N-arylation Organic chemistry photocatalysis Photocatalysts Photoredox catalysis radical reactions sulfoximines visible-light
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