Novel Porous Phosphorus⁻Calcium⁻Magnesium Coatings on Titanium with Copper or Zinc Obtained by DC Plasma Electrolytic Oxidation: Fabrication and Characterization
In this paper, the characteristics of new porous coatings fabricated at three voltages in electrolytes based on H₃PO₄ with calcium nitrate tetrahydrate, magnesium nitrate hexahydrate, and copper(II) nitrate trihydrate are presented. The SEM, energy dispersive spectroscopy (EDS), glow discharge optic...
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| Veröffentlicht in: | Materials 2018-09, Vol.11 (9), p.1680 |
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| creator | Rokosz, Krzysztof Hryniewicz, Tadeusz Gaiaschi, Sofia Chapon, Patrick Raaen, Steinar Matýsek, Dalibor Dudek, Łukasz Pietrzak, Kornel |
| description | In this paper, the characteristics of new porous coatings fabricated at three voltages in electrolytes based on H₃PO₄ with calcium nitrate tetrahydrate, magnesium nitrate hexahydrate, and copper(II) nitrate trihydrate are presented. The SEM, energy dispersive spectroscopy (EDS), glow discharge optical emission spectroscopy (GDOES), X-ray photoelectron spectroscopy (XPS), and XRD techniques for coating identification were used. It was found that the higher the plasma electrolytic oxidation (PEO) (micro arc oxidation (MAO)) voltage, the thicker the porous coating with higher amounts of built-in elements coming from the electrolyte and more amorphous phase with signals from crystalline Ca(H₂PO₄)₂∙H₂O and/or Ti(HPO₄)₂∙H₂O. Additionally, the external parts of the obtained porous coatings formed on titanium consisted mainly of Ti
, Ca
, Mg
and PO₄
, HPO₄
, H₂PO₄
, P₂O₇
as well as Zn
or copper Cu⁺/Cu
. The surface should be characterized by high biocompatibility, due to the presence of structures based on calcium and phosphates, and have bactericidal properties, due to the presence of zinc and copper ions. Furthermore, the addition of magnesium ions should accelerate the healing of postoperative wounds, which could lead to faster patient recovery. |
| doi_str_mv | 10.3390/ma11091680 |
| format | Article |
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, Ca
, Mg
and PO₄
, HPO₄
, H₂PO₄
, P₂O₇
as well as Zn
or copper Cu⁺/Cu
. The surface should be characterized by high biocompatibility, due to the presence of structures based on calcium and phosphates, and have bactericidal properties, due to the presence of zinc and copper ions. Furthermore, the addition of magnesium ions should accelerate the healing of postoperative wounds, which could lead to faster patient recovery.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma11091680</identifier><identifier>PMID: 30208598</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Biocompatibility ; Calcium ions ; Calcium nitrate ; Calcium phosphates ; Chemical elements ; Coatings ; Copper ; Electrolytes ; Glow discharges ; Magnesium ; Metals ; Nitrates ; Optical emission spectroscopy ; Oxidation ; Photoelectrons ; Plasma ; Spectrum analysis ; Titanium ; Wound healing ; X ray photoelectron spectroscopy ; Zinc</subject><ispartof>Materials, 2018-09, Vol.11 (9), p.1680</ispartof><rights>2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2018 by the authors. 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-4c82dde712ea1a641fef94007ee0a7e3286351bcdcdfbb1df7bba53ed6ba72843</citedby><cites>FETCH-LOGICAL-c406t-4c82dde712ea1a641fef94007ee0a7e3286351bcdcdfbb1df7bba53ed6ba72843</cites><orcidid>0000-0002-1412-1079</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6164096/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6164096/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30208598$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rokosz, Krzysztof</creatorcontrib><creatorcontrib>Hryniewicz, Tadeusz</creatorcontrib><creatorcontrib>Gaiaschi, Sofia</creatorcontrib><creatorcontrib>Chapon, Patrick</creatorcontrib><creatorcontrib>Raaen, Steinar</creatorcontrib><creatorcontrib>Matýsek, Dalibor</creatorcontrib><creatorcontrib>Dudek, Łukasz</creatorcontrib><creatorcontrib>Pietrzak, Kornel</creatorcontrib><title>Novel Porous Phosphorus⁻Calcium⁻Magnesium Coatings on Titanium with Copper or Zinc Obtained by DC Plasma Electrolytic Oxidation: Fabrication and Characterization</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>In this paper, the characteristics of new porous coatings fabricated at three voltages in electrolytes based on H₃PO₄ with calcium nitrate tetrahydrate, magnesium nitrate hexahydrate, and copper(II) nitrate trihydrate are presented. The SEM, energy dispersive spectroscopy (EDS), glow discharge optical emission spectroscopy (GDOES), X-ray photoelectron spectroscopy (XPS), and XRD techniques for coating identification were used. It was found that the higher the plasma electrolytic oxidation (PEO) (micro arc oxidation (MAO)) voltage, the thicker the porous coating with higher amounts of built-in elements coming from the electrolyte and more amorphous phase with signals from crystalline Ca(H₂PO₄)₂∙H₂O and/or Ti(HPO₄)₂∙H₂O. Additionally, the external parts of the obtained porous coatings formed on titanium consisted mainly of Ti
, Ca
, Mg
and PO₄
, HPO₄
, H₂PO₄
, P₂O₇
as well as Zn
or copper Cu⁺/Cu
. The surface should be characterized by high biocompatibility, due to the presence of structures based on calcium and phosphates, and have bactericidal properties, due to the presence of zinc and copper ions. Furthermore, the addition of magnesium ions should accelerate the healing of postoperative wounds, which could lead to faster patient recovery.</description><subject>Biocompatibility</subject><subject>Calcium ions</subject><subject>Calcium nitrate</subject><subject>Calcium phosphates</subject><subject>Chemical elements</subject><subject>Coatings</subject><subject>Copper</subject><subject>Electrolytes</subject><subject>Glow discharges</subject><subject>Magnesium</subject><subject>Metals</subject><subject>Nitrates</subject><subject>Optical emission spectroscopy</subject><subject>Oxidation</subject><subject>Photoelectrons</subject><subject>Plasma</subject><subject>Spectrum analysis</subject><subject>Titanium</subject><subject>Wound healing</subject><subject>X ray photoelectron spectroscopy</subject><subject>Zinc</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkktuFDEQhlsIRKKQDQdAltggpAE_etxtFkioSQApkFmEDRur_OhpR932YLsDw47DcApuw0nwJCEEvPHvql9fle2qqocEP2NM4OcTEIIF4S2-U-0TIfiCiLq-e0vvVYcpneOyGCMtFferPYYpbpei3a9-fAgXdkSrEMOc0GoIaTOEOKdf3392MGo3T0W9h7W3qWjUBcjOrxMKHp25DH4X_OLyUDKbjY0oRPTJeY1OVQbnrUFqi153aDVCmgAdjVbnGMZtdsXy1ZlCC_4FOgYVnb48IPAGdQNE0NlG9-0y-KC618OY7OH1flB9PD46694uTk7fvOtenSx0jXle1LqlxtiGUAsEeE1624sa48ZaDI1ltOVsSZQ22vRKEdM3SsGSWcMVNLSt2UH18oq7mdVkjbY-RxjlJroJ4lYGcPLfjHeDXIcLyQmvseAF8OQaEMPn2aYsJ5e0HUfwtjywpAQz3gha72o9_s96Huboy_Uk5bhhlHK6Az69cukYUoq2v2mGYLkbAPl3AIr50e32b6x_vpv9BoeFsgU</recordid><startdate>20180911</startdate><enddate>20180911</enddate><creator>Rokosz, Krzysztof</creator><creator>Hryniewicz, Tadeusz</creator><creator>Gaiaschi, Sofia</creator><creator>Chapon, Patrick</creator><creator>Raaen, Steinar</creator><creator>Matýsek, Dalibor</creator><creator>Dudek, Łukasz</creator><creator>Pietrzak, Kornel</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1412-1079</orcidid></search><sort><creationdate>20180911</creationdate><title>Novel Porous Phosphorus⁻Calcium⁻Magnesium Coatings on Titanium with Copper or Zinc Obtained by DC Plasma Electrolytic Oxidation: Fabrication and Characterization</title><author>Rokosz, Krzysztof ; Hryniewicz, Tadeusz ; Gaiaschi, Sofia ; Chapon, Patrick ; Raaen, Steinar ; Matýsek, Dalibor ; Dudek, Łukasz ; Pietrzak, Kornel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-4c82dde712ea1a641fef94007ee0a7e3286351bcdcdfbb1df7bba53ed6ba72843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Biocompatibility</topic><topic>Calcium ions</topic><topic>Calcium nitrate</topic><topic>Calcium phosphates</topic><topic>Chemical elements</topic><topic>Coatings</topic><topic>Copper</topic><topic>Electrolytes</topic><topic>Glow discharges</topic><topic>Magnesium</topic><topic>Metals</topic><topic>Nitrates</topic><topic>Optical emission spectroscopy</topic><topic>Oxidation</topic><topic>Photoelectrons</topic><topic>Plasma</topic><topic>Spectrum analysis</topic><topic>Titanium</topic><topic>Wound healing</topic><topic>X ray photoelectron spectroscopy</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rokosz, Krzysztof</creatorcontrib><creatorcontrib>Hryniewicz, Tadeusz</creatorcontrib><creatorcontrib>Gaiaschi, Sofia</creatorcontrib><creatorcontrib>Chapon, Patrick</creatorcontrib><creatorcontrib>Raaen, Steinar</creatorcontrib><creatorcontrib>Matýsek, Dalibor</creatorcontrib><creatorcontrib>Dudek, Łukasz</creatorcontrib><creatorcontrib>Pietrzak, Kornel</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rokosz, Krzysztof</au><au>Hryniewicz, Tadeusz</au><au>Gaiaschi, Sofia</au><au>Chapon, Patrick</au><au>Raaen, Steinar</au><au>Matýsek, Dalibor</au><au>Dudek, Łukasz</au><au>Pietrzak, Kornel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Porous Phosphorus⁻Calcium⁻Magnesium Coatings on Titanium with Copper or Zinc Obtained by DC Plasma Electrolytic Oxidation: Fabrication and Characterization</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2018-09-11</date><risdate>2018</risdate><volume>11</volume><issue>9</issue><spage>1680</spage><pages>1680-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>In this paper, the characteristics of new porous coatings fabricated at three voltages in electrolytes based on H₃PO₄ with calcium nitrate tetrahydrate, magnesium nitrate hexahydrate, and copper(II) nitrate trihydrate are presented. The SEM, energy dispersive spectroscopy (EDS), glow discharge optical emission spectroscopy (GDOES), X-ray photoelectron spectroscopy (XPS), and XRD techniques for coating identification were used. It was found that the higher the plasma electrolytic oxidation (PEO) (micro arc oxidation (MAO)) voltage, the thicker the porous coating with higher amounts of built-in elements coming from the electrolyte and more amorphous phase with signals from crystalline Ca(H₂PO₄)₂∙H₂O and/or Ti(HPO₄)₂∙H₂O. Additionally, the external parts of the obtained porous coatings formed on titanium consisted mainly of Ti
, Ca
, Mg
and PO₄
, HPO₄
, H₂PO₄
, P₂O₇
as well as Zn
or copper Cu⁺/Cu
. The surface should be characterized by high biocompatibility, due to the presence of structures based on calcium and phosphates, and have bactericidal properties, due to the presence of zinc and copper ions. Furthermore, the addition of magnesium ions should accelerate the healing of postoperative wounds, which could lead to faster patient recovery.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>30208598</pmid><doi>10.3390/ma11091680</doi><orcidid>https://orcid.org/0000-0002-1412-1079</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Materials, 2018-09, Vol.11 (9), p.1680 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6164096 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Biocompatibility Calcium ions Calcium nitrate Calcium phosphates Chemical elements Coatings Copper Electrolytes Glow discharges Magnesium Metals Nitrates Optical emission spectroscopy Oxidation Photoelectrons Plasma Spectrum analysis Titanium Wound healing X ray photoelectron spectroscopy Zinc |
| title | Novel Porous Phosphorus⁻Calcium⁻Magnesium Coatings on Titanium with Copper or Zinc Obtained by DC Plasma Electrolytic Oxidation: Fabrication and Characterization |
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