NMR Detection of Isomers Arising from Restricted Rotation of the C-N Amide Bond of N-Formyl-o-toluidine and N,N’-bis-Formyl-o-tolidine
Full and unambiguous assignment of all 1H- and 13C-NMR resonances of the isomers due to restricted C-N amide bond rotation of N-formyl-o-toluidine and N,N'-bis-formyl-o-tolidine in DMSO-d6 is reported. The cis-isomer predominates in the equilibrium mixture of both compounds as 1D-NOE difference...
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| Veröffentlicht in: | Molecules (Basel, Switzerland) Switzerland), 2002-08, Vol.7 (8), p.662-673 |
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| container_title | Molecules (Basel, Switzerland) |
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| creator | Quintanilla-Licea, Ramiro Colunga-Valladares, Juan F. Caballero-Quintero, Adolfo Rodríguez-Padilla, Cristina Tamez-Guerra, Reyes Gómez-Flores, Ricardo Waksman, Noemí |
| description | Full and unambiguous assignment of all 1H- and 13C-NMR resonances of the isomers due to restricted C-N amide bond rotation of N-formyl-o-toluidine and N,N'-bis-formyl-o-tolidine in DMSO-d6 is reported. The cis-isomer predominates in the equilibrium mixture of both compounds as 1D-NOE difference experiments show. |
| doi_str_mv | 10.3390/70800662 |
| format | Article |
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| title | NMR Detection of Isomers Arising from Restricted Rotation of the C-N Amide Bond of N-Formyl-o-toluidine and N,N’-bis-Formyl-o-tolidine |
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