C−H Borylation/Cross‐Coupling Forms Twisted Donor–Acceptor Compounds Exhibiting Donor‐Dependent Delayed Emission

Benzothiadiazole (BT) directed C−H borylation using BCl3, followed by B−Cl hydrolysis and Suzuki–Miyaura cross‐coupling enables facile access to twisted donor–acceptor compounds. A subsequent second C−H borylation step provides, on arylation of boron, access to borylated highly twisted D−A compounds...

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Veröffentlicht in:	Chemistry : a European journal 2018-07, Vol.24 (41), p.10521-10530
Hauptverfasser:	Crossley, Daniel L., Kulapichitr, Pakapol, Radcliffe, James E., Dunsford, Jay J., Vitorica‐Yrezabal, Inigo, Kahan, Rachel J., Woodward, Adam W., Turner, Michael L., McDouall, Joseph J. W., Ingleson, Michael J.
Format:	Artikel
Sprache:	eng
Schlagworte:	benzothiadiazole Boron Boron chlorides Boron compounds borylation Charge transfer Chemistry Computer applications Coupling (molecular) Emission analysis Energy gap Hydrolysis natural transition orbitals thermally activated delayed fluorescence
Online-Zugang:	Volltext
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