Site-selective formation of an iron(iv)-oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines

Iron(iv)-oxo species have been identified as the active intermediates in key enzymatic processes, and their catalytic properties are strongly affected by the equatorial and axial ligands bound to the metal, but details of these effects are still unresolved. In our aim to create better and more effic...

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Veröffentlicht in:	Chemical science (Cambridge) 2015-08, Vol.6 (8), p.5063-5075
Hauptverfasser:	İşci, Ümit, Faponle, Abayomi S, Afanasiev, Pavel, Albrieux, Florian, Briois, Valérie, Ahsen, Vefa, Dumoulin, Fabienne, Sorokin, Alexander B, de Visser, Sam P
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Chemistry Environment and Society Environmental Sciences Formations Fragmentation Ionization Iron Ligands Oxidants Oxidizing agents Terminals
Online-Zugang:	Volltext
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