Multivalence cooperativity leading to “all-or-nothing” assembly: the case of nucleation-growth in supramolecular polymers† †Electronic supplementary information (ESI) available: Experimental methods, including sample preparation for NMR, UV and electron microscopy experiments, the building up of the X-ray derived dimer structure, analysis of the binding of monovalent ligands, additional data on binding constant determination, effect of buffer concentration on polymer dimerization and detailed de

Multivalence cooperativity leading to “all-or-nothing” assembly: the case of nucleation-growth in supramolecular polymers† †Electronic supplementary information (ESI) available: Experimental methods, including sample preparation for NMR, UV and electron microscopy experiments, the building up of the X-ray derived dimer structure, analysis of the binding of monovalent ligands, additional data on binding constant determination, effect of buffer concentration on polymer dimerization and detailed de

All-or-nothing supramolecular polymerization: the role of multivalence cooperativity in multi-stranded polymers. All-or-nothing molecular assembly events, essential for the efficient regulation of living systems at the molecular level, are emerging properties of complex chemical systems that are lar...

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Veröffentlicht in:Chemical science (Cambridge) 2016-03, Vol.7 (7), p.4468-4475
Hauptverfasser: Lopez-Fontal, Elkin, Milanesi, Lilia, Tomas, Salvador
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
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