Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

Covering: up to the end of 2017 Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocon...

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Veröffentlicht in:	Natural product reports 2018-06, Vol.35 (6), p.559-574
Hauptverfasser:	Pritchett, Beau P, Stoltz, Brian M
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaloids Alkylation Aspidosperma - chemistry Catalysis Chemical reactions Chemical synthesis Enantiomers Heterocyclic Compounds, 4 or More Rings - chemical synthesis Heterocyclic Compounds, 4 or More Rings - chemistry Indole Alkaloids - chemical synthesis Indole Alkaloids - chemistry Indoles Molecular Structure Monoterpenes - chemical synthesis Monoterpenes - chemistry Palladium Stereoisomerism
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