Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine–Titanium Complex

Catalytic reduction of N2 to NH3 by a Ti complex has been achieved, thus now adding an early d‐block metal to the small group of mid‐ and late‐d‐block metals (Mo, Fe, Ru, Os, Co) that catalytically produce NH3 by N2 reduction and protonolysis under homogeneous, abiological conditions. Reduction of [...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-05, Vol.57 (21), p.6314-6318
Hauptverfasser:	Doyle, Laurence R., Wooles, Ashley J., Jenkins, Lucy C., Tuna, Floriana, McInnes, Eric J. L., Liddle, Stephen T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia Catalysis Chemical reduction Communication Communications dinitrogen reduction Extrusion Iron Metals nitrogen fixation phosphonium salts Protonation Titanium
Online-Zugang:	Volltext
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