Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity

Bis(phosphine)cobalt dialkyl complexes have been reported to be highly active in the hydrogenation of tri-substituted alkenes bearing hydroxyl substituents. Alkene substrates containing ether, ester, or ketone substituents show minimal reactivity, indicating an activating effect of the hydroxyl grou...

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Veröffentlicht in:	Chemical science (Cambridge) 2018, Vol.9 (22), p.4977-4982
Hauptverfasser:	Morello, Glenn R, Zhong, Hongyu, Chirik, Paul J, Hopmann, Kathrin H
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alkenes Catalysis Chemistry Chemistry: 440 Cobalt Ethers Hydrogenation Hydroxyl groups Kjemi: 440 Matematikk og Naturvitenskap: 400 Mathematics and natural science: 400 Organometallic compounds Substrates VDP
Online-Zugang:	Volltext
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