Quantitative model for rationalizing solvent effect in noncovalent CH-Aryl interactions

The strength of CH-aryl interactions (Δ G ) in 14 solvents was determined via the conformational analysis of a molecular torsion balance. The molecular balance adopted folded and unfolded conformers in which the ratio of the conformers in solution provided a quantitative measure of Δ G as a function...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (2), p.141-147
Hauptverfasser:	Emenike, Bright U, Bey, Sara N, Bigelow, Brianna C, Chakravartula, Srinivas V. S
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Extrapolation Gas phases Hydrogen bonds Mathematical analysis Mathematical models Solvation Solvent effect Solvents
Online-Zugang:	Volltext
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