Crystal structures of 2,4,6-tri-iodo-benzo-nitrile and 2,4,6-tri-iodo-phenyl isocyanide
The title crystals, C H I N, are isomorphous. Both mol-ecules lie across two crystallographic mirror planes and a twofold axis. The principal supra-molecular inter-action is centric (10) CN/NC⋯I short contacts involving both I atoms, with two contacts bis-ecting each cyano and iso-cyano group. These...
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| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2018-02, Vol.74 (Pt 2), p.98-102 |
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| container_issue | Pt 2 |
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| container_title | Acta crystallographica. Section E, Crystallographic communications |
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| creator | Noland, Wayland E Britton, Doyle Sutton, Gregory K Schneerer, Andrew K Tritch, Kenneth J |
| description | The title crystals, C
H
I
N, are isomorphous. Both mol-ecules lie across two crystallographic mirror planes and a twofold axis. The principal supra-molecular inter-action is centric
(10) CN/NC⋯I short contacts involving both
I atoms, with two contacts bis-ecting each cyano and iso-cyano group. These form ribbons along [010] and give rise to a planar sheet structure parallel to (100). All pairs of adjacent sheets have centric stacking, a mode not previously reported for sheets of this type. This study completes the series of
-2,4,6-trihalobenzo-nitriles, in which I atoms give the strongest CN⋯
and NC⋯
inter-actions (
= F, Cl, Br, I). |
| doi_str_mv | 10.1107/S2056989017018217 |
| format | Article |
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H
I
N, are isomorphous. Both mol-ecules lie across two crystallographic mirror planes and a twofold axis. The principal supra-molecular inter-action is centric
(10) CN/NC⋯I short contacts involving both
I atoms, with two contacts bis-ecting each cyano and iso-cyano group. These form ribbons along [010] and give rise to a planar sheet structure parallel to (100). All pairs of adjacent sheets have centric stacking, a mode not previously reported for sheets of this type. This study completes the series of
-2,4,6-trihalobenzo-nitriles, in which I atoms give the strongest CN⋯
and NC⋯
inter-actions (
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H
I
N, are isomorphous. Both mol-ecules lie across two crystallographic mirror planes and a twofold axis. The principal supra-molecular inter-action is centric
(10) CN/NC⋯I short contacts involving both
I atoms, with two contacts bis-ecting each cyano and iso-cyano group. These form ribbons along [010] and give rise to a planar sheet structure parallel to (100). All pairs of adjacent sheets have centric stacking, a mode not previously reported for sheets of this type. This study completes the series of
-2,4,6-trihalobenzo-nitriles, in which I atoms give the strongest CN⋯
and NC⋯
inter-actions (
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H
I
N, are isomorphous. Both mol-ecules lie across two crystallographic mirror planes and a twofold axis. The principal supra-molecular inter-action is centric
(10) CN/NC⋯I short contacts involving both
I atoms, with two contacts bis-ecting each cyano and iso-cyano group. These form ribbons along [010] and give rise to a planar sheet structure parallel to (100). All pairs of adjacent sheets have centric stacking, a mode not previously reported for sheets of this type. This study completes the series of
-2,4,6-trihalobenzo-nitriles, in which I atoms give the strongest CN⋯
and NC⋯
inter-actions (
= F, Cl, Br, I).</abstract><cop>England</cop><pub>International Union of Crystallography</pub><pmid>29850032</pmid><doi>10.1107/S2056989017018217</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-0861-822X</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Research Communications |
| title | Crystal structures of 2,4,6-tri-iodo-benzo-nitrile and 2,4,6-tri-iodo-phenyl isocyanide |
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