Rhodium-catalyzed regioselective addition of the ortho C-H bond in aromatic amides to the C-C double bond in α,β-unsaturated γ-lactones and dihydrofurans

An unprecedented C-H alkylation using α,β-unsaturated γ-lactones (butenolides) and dihydrofurans was achieved by the Rh-catalyzed reaction of benzamides. C-C bond formation occurs between the -position of the benzamide derivative and the γ-position of the butenolide or the α-position of the dihydrof...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (1), p.240-245
Hauptverfasser:	Shibata, Kaname, Chatani, Naoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzamide Bonding Carbon-carbon composites Chemistry Cleavage Derivatives Deuterium Insertion Rhodium
Online-Zugang:	Volltext
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