L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes

According to L-edge sum rules, the number of 3d vacancies at a transition metal site is directly proportional to the integrated intensity of the L-edge X-ray absorption spectrum (XAS) for the corresponding metal complex. In this study, the numbers of 3d holes are characterized quantitatively or semi...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2018-03, Vol.20 (12), p.8166-8176
Hauptverfasser:	Wang, Hongxin, Friedrich, Stephan, Li, Lei, Mao, Ziliang, Ge, Pinghua, Balasubramanian, Mahalingam, Patil, Daulat S
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Biological properties Configurations Coordination compounds Copper Dilution Enzymes INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Manganese Metallography Nickel Proteins Sum rules Superconductivity Uncertainty analysis X ray detectors
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