Mn‑, Fe‑, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

Mn‑, Fe‑, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to comp...

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Veröffentlicht in:Chemical reviews 2016-08, Vol.116 (15), p.8912-9000
Hauptverfasser: Crossley, Steven W. M, Obradors, Carla, Martinez, Ruben M, Shenvi, Ryan A
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
catalytic activity
Chemical reactions
iron
manganese
Molecules
olefin
Oxidation
synthesis gas
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container_title Chemical reviews
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creator Crossley, Steven W. M
Obradors, Carla
Martinez, Ruben M
Shenvi, Ryan A
description Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.
doi_str_mv 10.1021/acs.chemrev.6b00334
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subjects Catalysis
catalytic activity
Chemical reactions
iron
manganese
Molecules
olefin
Oxidation
synthesis gas
title Mn‑, Fe‑, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins
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