Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes

An asymmetric Ni-catalyzed reductive cross-coupling of (hetero)­aryl iodides and benzylic chlorides has been developed to prepare enantioenriched 1,1-diarylalkanes. As part of these studies, a new chiral bioxazoline ligand, 4-heptyl-BiOX (L1), was developed in order to obtain products in synthetical...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-04, Vol.139 (16), p.5684-5687
Hauptverfasser:	Poremba, Kelsey E, Kadunce, Nathaniel T, Suzuki, Naoyuki, Cherney, Alan H, Reisman, Sarah E
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes - chemical synthesis Alkanes - chemistry Catalysis Hydrocarbons, Chlorinated - chemistry Hydrocarbons, Iodinated - chemistry Molecular Structure Nickel - chemistry Oxidation-Reduction Stereoisomerism
Online-Zugang:	Volltext
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