Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles
Fluoropolymer nanocomposites of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) were prepared using fluorinated barium strontium titanate (Ba 1−x Sr x TiO 3 , BSTO) nanoparticles (NPs) by low-temperature synthesis using a modified liquid–solid solution process. The exact stoichiometry of...
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| Veröffentlicht in: | Scientific reports 2018-03, Vol.8 (1), p.4086-9, Article 4086 |
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| creator | Han, Wooje Kim, Taehee Yoo, Byungwook Park, Hyung-Ho |
| description | Fluoropolymer nanocomposites of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) were prepared using fluorinated barium strontium titanate (Ba
1−x
Sr
x
TiO
3
, BSTO) nanoparticles (NPs) by low-temperature synthesis using a modified liquid–solid solution process. The exact stoichiometry of as-synthesized BSTO NPs was confirmed by X-ray diffraction analysis along with lattice parameter calculations. The synthesized BSTO NPs were fluorinated using 2,2,2-trifluoroacetic acid as a fluorous ligand. The BSTO NPs showed high solubility in the fluorous system (polymer and solvent) on account of their modified surface. The root-mean-square roughness of the fluorinated BSTO/PVdF-HFP nanocomposite was 76 times lower than that of the nonfluorinated BSTO/PVdF-HFP nanocomposite. The dielectric constant of the fluorinated BSTO/PVdF-HFP nanocomposite exhibited Curie temperature behavior. The dielectric constant of the nanocomposite predicted using the modified Kerner model at room temperature agreed well with the experimental values. |
| doi_str_mv | 10.1038/s41598-018-22442-2 |
| format | Article |
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, BSTO) nanoparticles (NPs) by low-temperature synthesis using a modified liquid–solid solution process. The exact stoichiometry of as-synthesized BSTO NPs was confirmed by X-ray diffraction analysis along with lattice parameter calculations. The synthesized BSTO NPs were fluorinated using 2,2,2-trifluoroacetic acid as a fluorous ligand. The BSTO NPs showed high solubility in the fluorous system (polymer and solvent) on account of their modified surface. The root-mean-square roughness of the fluorinated BSTO/PVdF-HFP nanocomposite was 76 times lower than that of the nonfluorinated BSTO/PVdF-HFP nanocomposite. The dielectric constant of the fluorinated BSTO/PVdF-HFP nanocomposite exhibited Curie temperature behavior. The dielectric constant of the nanocomposite predicted using the modified Kerner model at room temperature agreed well with the experimental values.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-018-22442-2</identifier><identifier>PMID: 29511304</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/166/987 ; 639/301/1005/1007 ; Barium ; Dielectric constant ; Dielectric properties ; Electrical properties ; Humanities and Social Sciences ; Low temperature ; multidisciplinary ; Nanocomposites ; Nanoparticles ; Polymers ; Science ; Science (multidisciplinary) ; Stoichiometry ; Strontium ; Trifluoroacetic acid ; X-ray diffraction</subject><ispartof>Scientific reports, 2018-03, Vol.8 (1), p.4086-9, Article 4086</ispartof><rights>The Author(s) 2018</rights><rights>2018. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c511t-84b01a7e3b04a1db226586c66334ea77952ce0ae4358d654fda6628b559644c83</citedby><cites>FETCH-LOGICAL-c511t-84b01a7e3b04a1db226586c66334ea77952ce0ae4358d654fda6628b559644c83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5840133/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5840133/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,41096,42165,51551,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29511304$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Han, Wooje</creatorcontrib><creatorcontrib>Kim, Taehee</creatorcontrib><creatorcontrib>Yoo, Byungwook</creatorcontrib><creatorcontrib>Park, Hyung-Ho</creatorcontrib><title>Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Fluoropolymer nanocomposites of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) were prepared using fluorinated barium strontium titanate (Ba
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, BSTO) nanoparticles (NPs) by low-temperature synthesis using a modified liquid–solid solution process. The exact stoichiometry of as-synthesized BSTO NPs was confirmed by X-ray diffraction analysis along with lattice parameter calculations. The synthesized BSTO NPs were fluorinated using 2,2,2-trifluoroacetic acid as a fluorous ligand. The BSTO NPs showed high solubility in the fluorous system (polymer and solvent) on account of their modified surface. The root-mean-square roughness of the fluorinated BSTO/PVdF-HFP nanocomposite was 76 times lower than that of the nonfluorinated BSTO/PVdF-HFP nanocomposite. The dielectric constant of the fluorinated BSTO/PVdF-HFP nanocomposite exhibited Curie temperature behavior. The dielectric constant of the nanocomposite predicted using the modified Kerner model at room temperature agreed well with the experimental values.</description><subject>639/166/987</subject><subject>639/301/1005/1007</subject><subject>Barium</subject><subject>Dielectric constant</subject><subject>Dielectric properties</subject><subject>Electrical properties</subject><subject>Humanities and Social Sciences</subject><subject>Low temperature</subject><subject>multidisciplinary</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Polymers</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Stoichiometry</subject><subject>Strontium</subject><subject>Trifluoroacetic acid</subject><subject>X-ray diffraction</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp9UU1v1DAUjBCIVqV_gAOyxKUcAv7e5IIEpQtIFVRiOVuO89J15djBdkr3n_Tn4t0tpXDAsuSxZt689zRV9Zzg1wSz5k3iRLRNjUlTU8o5remj6pBiLmrKKH38AB9Uxyld4XIEbTlpn1YHtBWEMMwPq9vV7HXnAH2w4MDkaA26iGGCmC0kFAZ0Edzm5Nr6jbM9eBjcHGJBtQn1Gm707h-mcjeu0K_Q0roxoZ82r9HZ2EHfQ4-WuyKvc8HvdbTziL7lGHzeopXNekuhL9qHSZfGxkF6Vj0ZtEtwfPceVd-XZ6vTT_X514-fT9-d16askOuGd5joBbAOc036jlIpGmmkZIyDXixaQQ1gDZyJppeCD72WkjadEK3k3DTsqHq7953mboTegM9ROzVFO-q4UUFb9Tfj7VpdhmslGo4JY8Xg5M4ghh8zpKxGmww4pz2EOSmKCZFECMGL9OU_0qswR1_W26lKIAu2VdG9ysSQUoThfhiC1TZ7tc9elezVLntFS9GLh2vcl_xOugjYXpAK5S8h_un9H9tfgOK9jA</recordid><startdate>20180306</startdate><enddate>20180306</enddate><creator>Han, Wooje</creator><creator>Kim, Taehee</creator><creator>Yoo, Byungwook</creator><creator>Park, Hyung-Ho</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20180306</creationdate><title>Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles</title><author>Han, Wooje ; Kim, Taehee ; Yoo, Byungwook ; Park, Hyung-Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c511t-84b01a7e3b04a1db226586c66334ea77952ce0ae4358d654fda6628b559644c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>639/166/987</topic><topic>639/301/1005/1007</topic><topic>Barium</topic><topic>Dielectric constant</topic><topic>Dielectric properties</topic><topic>Electrical properties</topic><topic>Humanities and Social Sciences</topic><topic>Low temperature</topic><topic>multidisciplinary</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Polymers</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Stoichiometry</topic><topic>Strontium</topic><topic>Trifluoroacetic acid</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Wooje</creatorcontrib><creatorcontrib>Kim, Taehee</creatorcontrib><creatorcontrib>Yoo, Byungwook</creatorcontrib><creatorcontrib>Park, Hyung-Ho</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Wooje</au><au>Kim, Taehee</au><au>Yoo, Byungwook</au><au>Park, Hyung-Ho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2018-03-06</date><risdate>2018</risdate><volume>8</volume><issue>1</issue><spage>4086</spage><epage>9</epage><pages>4086-9</pages><artnum>4086</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Fluoropolymer nanocomposites of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) were prepared using fluorinated barium strontium titanate (Ba
1−x
Sr
x
TiO
3
, BSTO) nanoparticles (NPs) by low-temperature synthesis using a modified liquid–solid solution process. The exact stoichiometry of as-synthesized BSTO NPs was confirmed by X-ray diffraction analysis along with lattice parameter calculations. The synthesized BSTO NPs were fluorinated using 2,2,2-trifluoroacetic acid as a fluorous ligand. The BSTO NPs showed high solubility in the fluorous system (polymer and solvent) on account of their modified surface. The root-mean-square roughness of the fluorinated BSTO/PVdF-HFP nanocomposite was 76 times lower than that of the nonfluorinated BSTO/PVdF-HFP nanocomposite. The dielectric constant of the fluorinated BSTO/PVdF-HFP nanocomposite exhibited Curie temperature behavior. The dielectric constant of the nanocomposite predicted using the modified Kerner model at room temperature agreed well with the experimental values.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>29511304</pmid><doi>10.1038/s41598-018-22442-2</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 639/166/987 639/301/1005/1007 Barium Dielectric constant Dielectric properties Electrical properties Humanities and Social Sciences Low temperature multidisciplinary Nanocomposites Nanoparticles Polymers Science Science (multidisciplinary) Stoichiometry Strontium Trifluoroacetic acid X-ray diffraction |
| title | Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles |
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